Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

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Поиск по журналу

Журнал структурной химии

2013 год, номер Приложение 1

SINGLE-CRYSTAL 1H NMR DATA AND HYDROGEN ATOM DISORDER IN LAWSONITE, CaAl2[Si2O7](OH)2Г—H2O

S.G. Kozlova, S.P. Gabuda
A.V. Nikolaev Institute of Inorganic Chemistry, SB RAS, 630090, Russia, Novosibirsk, Lavrentiev ave., 3
sgk@niic.nsc.ru
Ключевые слова: 1H NMR, hydrogen atom, disorder, lawsonite
Страницы: 147-151
Подраздел: ЯМР СПЕКТРОСКОПИЯ

Аннотация

The dynamic structure of hydrogen sublattice in lawsonite, CaAl2[Si2O7](OH)2×H2O is studied by the solid-state proton magnetic resonance (1H NMR) spectroscopy of single crystal at room temperature. It is shown that both encapsulated water molecules, and hydroxyl OH-groups undergoes the rocking librations of the amplitudes of ~20° for H2O, and ~40° for hydroxyls.
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