Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

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Яндекс.Метрика

Поиск по журналу

Журнал структурной химии

2015 год, номер 4

CRYSTAL STRUCTURE AND LUMINESCENT PROPERTIES OF A ONE-DIMENSIONAL Cd(II) COORDINATION POLYMER CONSTRUCTED BY 4,4'-DI-TERT-BUTYL-2,2'-BIPYRIDINE AND 5-TERT-BUTYL ISOPHTHALIC ACID

X.J. Xu, J. Wang
Yancheng Teachers University, Yancheng, Jiangsu, P.R. China
wjyctu@gmail.com
Ключевые слова: Cd(II) complex, 4,4'-di-tert-butyl-2,2'-bipyridine, 5-tert-butyl isophthalic acid, crystal structure, luminescence
Страницы: 831-835
Подраздел: КРАТКИЕ СООБЩЕНИЯ

Аннотация

A one-dimensional Cd(II) complex [Cd(Bu2bpy)(tbip)×H2O]n (1) (Bu2bpy = 4,4'-di-tert-butyl-2,2'-bipyridine, H2tbip = 5-tert-butyl isophthalic acid) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. The single crystal X-ray diffraction analysis reveals that complex 1 is a one-dimensional double chain polymer based on {Cd2(OCO)2} dimeric kernels with a Cd⋯Cd separation of 4.3197(7) Å. The thermal stability and luminescent properties of the title complex are briefly investigated.

DOI: 10.15372/JSC201504027