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Chemistry for Sustainable Development

2014 year, number 3

Changing the Structural and Mechanical Properties of Hydrocarbons after a High-Frequency Acoustic Impact

R. V. ANUFRIEV1 and G. I. VOLKOVA1,2
1Institute of Petroleum Chemistry, Siberian Branch of the Russian Academy of Sciences,
Pr. Akademicheskiy 4, Tomsk 634021 (Russia)
E-mail: slaymer89@mail.ru
2National Research Tomsk State University,
Prospekt Lenina 36, Tomsk 634050 (Russia)
E-mail: pat@ipc.tsc.ru
Keywords: resin, oil paraffin, ultrasonic treatment, viscosity, hydrodynamic drag reduction, microscopy, gas-liquid chromatography
Pages: 303–308

Abstract

An effect of ultrasonic treatment exerted on the structure and mechanical properties of polyacrylamide, polyhexene, polyethylene and oil paraffin solutions was investigated. Schemes are proposed for the destruction of polyhexene and polyethylene via a radical mechanism. It has been found that the acoustic impact on the oil paraffin solution in decane does not affect the nature of the molecular mass distribution for n-alkanes, but results in increasing the temperature of phase transitions and changing the shape of crystallites.