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Chemistry for Sustainable Development

2011 year, number 3

Investigation of the Kinetics of U3O8 Reduction by Hydrogen and Ammonia under Non-Isothermal Conditions

E. V. SIDOROV and V. L. SOFRONOV
Seversk Technological Institute, Branch State Budget Educational Institution of Higher Professional Education “National Research Nuclear University MEPhl”
ev_sid@mail.ru
Keywords: triuranium octoxide, reduction, hydrogen, ammonia, uranium dioxide, temperature, kinetics, non-isothermal conditions
Pages: 315–319

Abstract

The possibility of preliminary reduction of U3O8 with hydrogen and ammonia before its fluorination for the purpose of increasing uranium (IV) content in the product is considered. Results of the investigation aimed at the determinaiton of optimal temperatures and the kinetics of U3O8 reduction under non-isothermic conditions by means of temperature-programmed reduction are presented.