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Chemistry for Sustainable Development

2008 year, number 3

Combined Extraction-Electrochemical Process of Bromine Recovery from Natural Brines

D. V. KUZMIN, V. I. KUZMIN and G. L. PASHKOV
Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk (Russia)
Keywords: chloride brines, bromine salts, extraction, electrolysis
Pages: 273-279

Abstract

New technology of bromine recovery from bromine-containing brines is proposed. The technology is based on the anode decomposition of metal chloride, oxidation of bromine with escaping chlorine, extraction transfer of bromine from the anode electrolyte to the recycle catholyte and reduction of bromine on a porous cathode. Commercial products of the proposed method are individual salts of bromine. It was demonstrated that the develop process is safe and involves low energy and reagent consumption.