Издательство СО РАН

Издательство СО РАН

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Поиск по журналу

Журнал структурной химии

2017 год, номер 7

CHARACTERIZATION, CRYSTAL STRUCTURE DETERMINATION, AND LUMINESCENT PROPERTIES OF [Pd(4,4'-bit)Cl2]

A. Ebadi, S. Shojaei
Department of Chemistry, Kazerun Branch, Islamic Azad University, Kazerun, Iran
ebadiamin58@gmail.com
Ключевые слова: crystal structure, palladium(II) complex, 4,4'-bithiazole, luminescent properties
Страницы: 1496-1501

Аннотация

Сomplex [Pd(4,4¢-bit)Cl2] (1) is synthesized by the reaction of PdCl2 and 4,4¢-bithiazole (4,4¢-bit) in acetonitrile and crystallized by vapor diffusion of methanol into a dimethyl sulfoxide solution of the complex. This complex is thoroughly characterized by elemental analysis, IR, 1H NMR, UV-Vis, and luminescence spectroscopy and its structure is studied by the single crystal X-ray diffraction method. The X-ray structure determination shows that in the structure of this complex, the Pd(II) atom is four-coordinated in a slightly distorted square-planar configuration by two nitrogen atoms from a bidentate 4,4¢-bithiazole ligand and two chloride ions.