Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

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Поиск по журналу

Журнал структурной химии

2017 год, номер 7

A NOVEL DINUCLEAR CuII COMPLEX BASED ON FLEXIBLE BIS(TRIAZOLE): SYNTHESIS, STRUCTURE AND PHYSICAL PROPERTIES

X.-J. Xu, X. Fang, H.-N. Yu, Z. Zhou, J. Wang
School of Chemistry & Environmental Engineering, Yancheng Teachers University, Yancheng, Jiangsu, P.R. China
xxjyctu@hotmail.com
Ключевые слова: Cu(II) complex, oxybis(ethane)bis(1H-triazole), dinuclear, photocatalytic activity
Страницы: 1479-1481

Аннотация

New dinuclear copper(II) complex [Cu2(BTE)2(N3)4] (1) (BTE = 1,1¢-(2,2¢-oxybis(ethane-2,1-diyl))bis(1H-1,2,4-triazole)) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. Single crystal X-ray diffraction reveals that complex 1 is a centrosymmetric dinuclear Cu(II) cluster unit with a Cu-Cu separation of 3.267(6) Å. In addition, complex 1 exhibits a high photocatalytic degradation activity for the degradation of rhodamine B.