CRYSTAL STRUCTURE OF 2-[BENZYL-(7-OXO-CYCLOHEPTA-1,3,5-TRIENYL)-AMINO]-N-CYCLOHEXYLPROPANAMIDE
A. Ramazani1, S.W. Joo2, I. Amini3, K. Ељlepokura4, T. Lis4, A. Souldozi1
1Islamic Azad University, Zanjan, Iran aliramazani@gmail.com 2Yeungnam University, Republic of Korea swjoo@yu.ac.kr 3Payame Noor University, Tehran, Iran 4University of Wrocław, Wrocław, Poland
Ключевые слова: single crystal X-ray structure, smiles rearrangement, Ugi-type coupling, tropolone, cyclohexylisocyanide, benzyl amine, acetaldehyde, Ugi-Smiles-type reaction
Страницы: 498-501 Подраздел: КРАТКИЕ СООБЩЕНИЯ
Аннотация
The title compound 2-[benzyl-(7-oxo-cyclohepta-1,3,5-trienyl)-amino]-N-cyclohexylpropanemide is synthesized and studied by the single crystal X-ray diffraction method. The structure of the product was confirmed by IR, 1H and 13C NMR spectroscopy, and mass spectrometry. The tropone oxygen atom plays an important role in the solid-state molecular structure stabilization by being involved in intramolecular N-H⋯O and C-H⋯O contacts.
DOI: 10.15372/JSC20150310 |