Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

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Яндекс.Метрика

Поиск по журналу

Переход горения в детонацию в бензино-воздушных смесях

2015 год, номер 2

STRUCTURAL CHARACTERIZATION OF A NEW COPPER(II) COMPLEX OF 1,10–PHENANTHROLINE AND BENZOATE [Cu(phen)(C6H5CO2)2]


Ключевые слова: copper(II) carboxylates, 1,10-phenanthroline, benzoic acid
Страницы: 405-409
Подраздел: КРАТКИЕ СООБЩЕНИЯ

Аннотация

A new mixed-ligand copper(II) complex of 1,10-phenanthroline (phen) and benzoate ligands having the general formula [Cu(phen)(C6H5CO2)2] is prepared and its crystal structure is determined by X-ray crystallography. The complex exists in the monomeric form; the coordination environment around the copper(II) ion is square planar, with the pair of monodentate benzoate ligands being in a cis disposition. In the crystal, the molecules are linked into [001] chains by weak C-H⋯O interactions; no aromatic π-π stacking occurs.