CRYSTAL AND MOLECULAR STRUCTURE OF DICESIUM BIS(MALONATO)-DI-μ-SULPHIDO-BIS[OXOMOLYBDATE(V)] DIHYDRATE: Cs2[Mo2O2S2(MALONATE)2(H2O)2]·2H2O
Fadel M. Abou1, N. Watfa1,2, S. Floquet1, J. Marrot1, M. Awada1, A. Hijazi2, D. Naoufal2, E. Cadot1
1Institut Lavoisier de Versailles, Versailles Cedex, France
sebastien.floquet@uvsq.fr
2Lebanese University, Hadath, Beirut, Lebanon
Ключевые слова: chalcogenide, thiometalate, polyoxometalate, molybdenum, sulfur
Страницы: 247-252
Подраздел: САМОСБОРКА И СУПРАМОЛЕКУЛЯРНАЯ ОРГАНИЗАЦИЯ КООРДИНАЦИОННЫХ СОЕДИНЕНИЙ
Аннотация
The compound Cs2[Mo2O2S2(C3H2O4)2(H2O)2]×2H2O has been synthetized and isolated as single crystals. It crystallizes in the Pnma space group and the structural analysis reveals that all the components are held together to build a 3D compact layered network, evidencing that {Mo2O2S2}–based molecular complexes can be used as building units for the elaboration of metal organic frameworks materials.
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