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Atmospheric and Oceanic Optics

2021 year, number 4

Nonpolynomial representation of N2-, O2-, air-, and self-broadening coefficients of ozone lines

V.I. Starikov1, S.N. Mikhailenko2
1Tomsk State University of Control Systems and Radioelectronics, Tomsk, Russia
2V.E. Zuev Institute of Atmospheric Optics of Siberian Branch of the Russian Academy of Science, Tomsk, Russia
Keywords: ozone molecule, spectral line broadening, nonpolynomial representation

Abstract

The parameters of a nonpolynomial analytical model γ (sur) are determined from the fitting of the known experimental data on the N2-, O2-, air-, and self-broadening coefficients of the ozone absorption lines. The model gives a finite value for the coefficients γ in asymptotic. The average accuracy of experimental data description is better than 3% for several thousand lines with quantum numbers up to J = 60. The results of the calculations based on the model suggested are compared to the results obtained using polynomial representations for the broadening coefficients.