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Chemistry for Sustainable Development

2014 year, number 2

Study of the Biodegradability of Anion-Active Surfactants on the Ground of Polyunsaturated Fatty Acids

V. M. ABBASOV1, L. I ALIEVA1, Z. G. ASADOV1, E. V. RAKHMANOV2 and I. G. NAZAROV3
1Mamedaliev Institute of Petrochemical Processes, Azerbaijan NAS, Pr. Khojali 30, Baku AZ1025 (Azerbaijan)
E-mail: leylufer-ipcp@rambler.ru
2Lomonosov Moscow State University, Leninskiye Gory, GSP-1, Moscow 119991 (Russia)
3Lomonosov Moscow State University, Baku Branch, Ul. B. Vahabzade, 14, Baku AZ 1143 (Azerbaijan)
Keywords: biodegradability, surfactants, fatty acids, linolenic acid, salts of sulpho acids, petroleum collecting
Pages: 105–111

Abstract

Anion-active surfactants on the ground of sulpho derivatives of a mixture of fatty acids isolated from corn oil and individual linolenic acid were obtained. Physicochemical properties of surfactants and calcium salts synthesized on their ground have been defined. Research with thin (0.16–0.17 mm) films of petroleum on the surface of various waters (fresh, distilled, sea) has shown that these salts as 5 and 10 % solutions of ethanol possess good petroleum collecting and petroleum dispersing properties. It has been established that 0.025 and 0.05 % solutions of calcium salts are biodegradable.