Synthesis and Thermal Properties of Pd(II) Compounds with Perfluorinated Aromatic Thiols and Thiol Derivatives of Phenol
S. V. LARIONOV1, T. G. LEONOVA1, n. i. bATRACHENKO1, I. V. KOROL’KOV1, R. F. KLEVTSOVA1, L. A. GLINSKAYA1, V. E. PLATONOV1, A. P. KRYSIN2, A. M. MAKSIMOV2 and V. P. FADEEVA2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences,
Pr. Akademika Lavrentyeva 3, Novosibirsk 630090 (Russia)
E-mail: lar@che.nsk.su
2Vorozhtsov Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences,
Pr. Akademika Lavrentyeva 9, Novosibirsk 630090 (Russia)
(Received December 26, 2005)
Pages: 147-155
Abstract
Compounds of Pd(II) of the PdL2 formulation with perfluorinated thiols of aromatic series 4-CF3C6F4SH (HL1), 2,4-(CF3)2C6F3SH (HL2), 4-nonafluorodiphenylthiol C6F5C6F4SH (HL3), 2-heptafluoronaphthalenethiol C10F7SH (HL4), and phenolic antioxidant 2,6-di(tert-C4H9)-4-(CH2)3SH (HL5) have been obtained that feature a rather weak smell for mercaptans. The HL3 structure has been determined by the X-ray diffraction analysis method. Thermal properties of Pd(L1)2
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