High resolution laser spectroscopy of the ozone molecule at the dissociation threshold
N.N. Lavrentieva, A.S. Dudaryonok
V.E. Zuev Institute of Atmospheric Optics of Siberian Branch of the Russian Academy of Science, Tomsk, Russia
Keywords: profile parameters, line broadening, temperature exponent
Abstract
Self- and air-broadening coefficients of nitrogen dioxide lines are calculated. The calculations are performed at a room temperature ( Т = 296 K) for ~ 29000 lines, rotational quantum numbers vary in the range up to 87 for N and up to 20 Ka . The temperature exponents are calculated for every line. The resulted parameters are compared with the literature and spectroscopic database. The calculations are made by two approaches: the semi-empirical method and energy difference method.
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