Features of molecular-beam mass spectrometry registration of clusters in underexpanded supersonic jets
A.E. Zarvin, V.V. Kalyada, and V.E. Khudozhitkov
Novosibirsk State University, Novosibirsk, Russia
E-mail: zarvin@phys.nsu.ru
Keywords: supersonic jet, molecular beam, condensation, cluster formation, mass-spectrometry, cluster ionization
Pages: 671–681
Abstract
The
structure of clustered supersonic underexpanded jets of molecular nitrogen and
argon was measured by the method of molecular beam mass-spectrometry.
Peculiarities of application of the molecular beam methods for recording the
supersonic rarefied gas jets under the conditions of weak and developed
condensation (i.e., in the presence of small and large clusters in jets) have
been discovered, identified, and studied. An unusual shape of longitudinal and
transverse cross sections of the clustered supersonic jets was revealed and
explained when scanning with a molecular-beam system. It has been
determined that small clusters and monomers are the sources of double-ionized
monomers available near the flow axis, and dimer ions at the early stages of
condensation, whereas another mechanism of such ion formation dominates, when
large clusters area available in the flow. A marker for fixing the stage
of formation of small clusters in a supersonic flow is proposed.
DOI: 10.1134/S0869864317050031
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