Synthesis and Thermal Properties of Pd(II) Compounds with Perfluorinated Aromatic Thiols and Thiol Derivatives of Phenol
a:2:{s:4:"TYPE";s:4:"HTML";s:4:"TEXT";s:272:"S. V. LARIONOV1, T. G. LEONOVA1, n. i. bATRACHENKO1, I. V. KOROL’KOV1, R. F. KLEVTSOVA1, L. A. GLINSKAYA1, V. E. PLATONOV1, A. P. KRYSIN2, A. M. MAKSIMOV2 and V. P. FADEEVA2";}
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences,
Pr. Akademika Lavrentyeva 3, Novosibirsk 630090 (Russia)
E-mail: lar@che.nsk.su
2Vorozhtsov Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences,
Pr. Akademika Lavrentyeva 9, Novosibirsk 630090 (Russia)
(Received December 26, 2005)
Pages: 147-155
Abstract
Compounds of Pd(II) of the PdL2 formulation with perfluorinated thiols of aromatic series 4-CF3C6F4SH (HL1), 2,4-(CF3)2C6F3SH (HL2), 4-nonafluorodiphenylthiol C6F5C6F4SH (HL3), 2-heptafluoronaphthalenethiol C10F7SH (HL4), and phenolic antioxidant 2,6-di(tert-C4H9)-4-(CH2)3SH (HL5) have been obtained that feature a rather weak smell for mercaptans. The HL3 structure has been determined by the X-ray diffraction analysis method. Thermal properties of Pd(L1)2
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