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Chemistry for Sustainable Development

2003 year, number 5

Distribution of Polarization and Thickness of Reaction Region in Porous Water-Proofed Electrodes in the Intrakinetic Mode

YURI V. SALTYKOV and VASILIY L. KORNIENKO
Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences,
Ul. K. Marxa 42, Krasnoyarsk 660049 (Russia) E-mail: kvl@icct.ru
Pages: 749-753

Abstract

The analysis of the solution of the differential equation for a porous electrode operating in the intrakinetic mode under exponential kinetics is carried out. The distribution of polarization and thickness of the reaction region in porous water-proofed electrodes of different thickness operating under the same conditions is considered. A more accurate formulation of the intermediate-thickness electrode is presented; its specific features in comparison with a thick and a thin electrode are analyzed.