Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

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Журнал структурной химии

2015 год, номер 5

CRYSTAL STRUCTURE OF COPPER(I) THIOSEMICARBAZONE COMPLEX [CuI(PPh3)(catsc)]

E. Shahsavani1, N. Feizi2, V. Eigner3, M. Dusek3, A.D. Khalaji4
1Payame Noor University, Mashhad, Iran
2Institute of Chemical Technology, Prague, Czech Republic
3Institute of Physics of the ASCR, Prague 8, Czech Republic
4Golestan University, Gorgan, Iran
alidkhalaji@yahoo.com
Ключевые слова: copper(I), thiosemicarbazone, crystal structure, single crystal
Страницы: 1061-1065
Подраздел: КРАТКИЕ СООБЩЕНИЯ

Аннотация

In this paper, we report the preparation of a four-coordinated copper(I) thiosemicarbazone complex [CuI(PPh 3)(catsc)] from the reaction of PPh 3 and catsc (3-phenylpropenalthiosemicarbazone) with CuI. The synthesized complex is characterized by elemental analyses (CHNS) and FT-IR spectroscopy. The crystal structure of [CuI(PPh 3)(catsc)] is investigated by single crystal X-ray diffraction. The catsc coordinates to the copper(I) ion as a bidentate ligand via the N and S atoms. The complex has a distorted tetrahedral coordination geometry.

DOI: 10.15372/JSC20150527