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Chemistry for Sustainable Development

2024 year, number 1

Rheological and Colloid-Structural Behaviour of High-Viscosity Crude Oil and Emulsion after Wave Action

YU. V. LOSKUTOVA, N. V. YUDINA
Institute of Petroleum Chemistry, Siberian Branch of the Russian Academy of Sciences, Tomsk, Russia
Keywords: crude oil, emulsion, electromagnetic field, low-frequency acoustic processing, viscosity, viscous flow activation energy
Pages: 59-69

Abstract

One of the main problems in oil production is the formation of stable oil-water emulsions that cause corrosion of pipelines, malfunction of pumping equipment, and poisoning of catalysts at refineries. The features of the viscosity-temperature behaviour of high-viscosity resinous crude oil from the Russkoye field (Yamal-Nenets autonomous district) and its 30 wt% emulsion after exposure to electromagnetic and low-frequency acoustic fields are investigated. Electromagnetic treatment of crude oil leads to a decrease in the phase transition temperature and the yield strength coefficient. Low-frequency acoustic processing of the emulsion is accompanied by a decrease in the effective viscosity and the yield strength coefficient. After a complex wave action, the viscosity-temperature characteristics of crude oil continue to fall, and the stability of the formed emulsions decreases due to the intense coalescence of water-phase droplets. It is shown that the amount of released asphaltenes in oil-containing systems decreases after wave treatment. On the contrary, after a complex impact, their content in crude oil increases, while in the emulsion it continues to decrease. This is likely to occur due to the release of hydrocarbons occluded in the asphaltene structure into the liquid oil phase.

DOI: 10.15372/CSD2024531
EDN: KLWHKH