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Geography and Natural Resources

2019 year, number 3

METHANE EMISSION FROM THE SURFACE OF THE MOZHAISK VALLEY-TYPE RESERVOIR

M.G. GRECHUSHNIKOVA1,2, I.A. REPINA1,3, V.M. STEPANENKO1, V.S. KAZANTSEV3, A.YU. ARTAMONOV4, V.A. LOMOV1
1M.V. Lomonosov Moscow State University, 119991, Moscow, Leninskie gory, 1, Russia
allavis@mail.ru; 119333. Moscow. ul.Gubkina. 3. Russia
2Institute of Water Problems, Russian Academy of Sciences
3A.M. Obukhov Institute of Atmospheric Physics, Russian Academy of Sciences, 119017, Moscow, per. Pyzhevskii, 3, Russia
repina@ifaran.ru
4A.M. Obukhov Institute of Atmospheric Physics, Russian Academy of Sciences
sailer@ifaran.ru
Keywords: гидрологический режим, водообмен, содержание метана, растворенный кислород, плавучие ка меры, бескислородные условия, hydrological regime, water exchange, methane content, dissolved oxygen, floating chambers, oxygen-free condi tions

Abstract

This article deals with spatio-temporal changes in methane emission from the surface of the Mozhaisk reservoir. Seasonal changes in the content and specific flow of methane were revealed for different morphological areas of the reservoir, based on field observation data obtained in 2015-2018. In the low-flow Mozhaisk reservoir, the methane content in the surface and bottom layers of the deep-water areas at the end of the summer stratification period may differ by three orders of magnitude. According to results from measuring with floating chambers in the сentral area of the reservoir from early June to the end of the period of direct stratification (August-September) the total methane flow increased from less than 1 to 16 mg С-СН4 / (m 2 ⋅ hour). Time-coin cident measurements with floating chambers of two types revealed characteristic values of the methane flow components and their change during the sampling period. It was found that at the period of stratification the diffusive flux predominates with the mean values 0,2 mg С-СН4 / (m 2 ⋅ hour). A further increase in the total methane flux is associated with an increase of its bubble component. According to calculations, the diffusive flux reaches its maximum values in late summer in the shallow zone of the reservoir. It is established that a significant increase of the values of the total methane flux is observed when the upper boundary of the oxygen-free zone reaches the lower boundary of the epilimnion. The specific methane flux density reaches its largest values prior to destruction of direct stratification. Comparison of field measurements with literature data showed that the magnitude of emission from reservoirs with a slow water exchange in the temperate zone can be underestimated in estimations of global methane emission.