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Chemistry for Sustainable Development

2018 year, number 5

Modelling Synthesis via Combustion of Composites Based on Mechanoactivated Ti–C, Ti–B, and Ti–Si Powder Systems

YU. A. CHUMAKOV1 and A. G. KNYAZEVA1,2
1Institute of Physics of Strength and Materials Science, Siberian Branch, Russian Academy of Sciences, Tomsk, Russia
E-mail: chya@ispms.tsc.ru
2National research Tomsk Polytechnic University, Tomsk, Russia
Keywords: mechanical activation, composites synthesis, solid-phase combustion, modelling
Pages: 515-523

Abstract

A model of synthesis was proposed and theoretically investigated via combustion of a composite in mechanically activated Ti–C, Ti–B, and Ti–Si powder mixtures. The effect of mechanical activation on synthesis modes was explored by introducing special activation parameter. As demonstrated by calculations, with its increase, the maximum temperature in the reaction wave is decreased during the reaction; combustion concentration limits are expanded and the propagation velocity of the reaction front is increased.

DOI: 10.15372/CSD20180510