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Издательство СО РАН

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Поиск по журналу

Журнал структурной химии

2016 год, номер 8

NOVEL REPAGLINIDE COMPLEXES WITH MANGANESE(II), IRON(III), COPPER(II) AND ZINC(II): SPECTROSCOPIC, DFT CHARACTERIZATION AND ELECTROCHEMICAL BEHAVIOUR

S. Sadaoui-Kacel1,2, S. Zaater1, N. Bensouilah3, S. Djebbar1
1Universite de Houari Boumediene Sciences et Technologie, Alger, Algerie
safia.djebbar@netcourrier.com
2Universite de M¢hamed Bougara, Boumerdes, Algerie
3Universite 8 Mai 1945, Guelma, Algerie
Ключевые слова: metal complexes, repaglinide ligand, synthesis, DFT, electrochemical behavior
Страницы: 1613-1624

Аннотация

Novel transition metal complexes with the repaglinide ligand [2-ethoxy-4-[N-[1-(2piperidinophenyl)-3-methyl-1-1butyl] aminocarbonylmethyl]benzoic acid] (HL) are prepared from chloride salts of manganese(II), iron(III), copper(II), and zinc(II) ions in water-alcoholic media. The mononuclear and non-electrolyte [M(L)2(H2O)2]× n H2O (M = Mn2+, n = 2, M = Cu2+, n = 5 and M = Zn2+, n = 1) and [M(L)2(H2O)(OH)]×H2O (M = Fe3+) complexes are obtained with the metal:ligand ratio of 1:2 and the L-deprotonated form of repaglinide. They are characterized using the elemental and molar conductance. The infrared, 1H and 13C NMR spectra show the coordination mode of the metal ions to the repaglinide ligand. Magnetic susceptibility measurements and electronic spectra confirm the octahedral geometry around the metal center. The experimental values of FT-IR, 1H, NMR, and electronic spectra are compared with theoretical data obtained by the density functional theory (DFT) using the B3LYP method with the LANL2DZ basis set. Analytical and spectral results suggest that the HL ligand is coordinated to the metal ions via two oxygen atoms of the ethoxy and carboxyl groups. The structural parameters of the optimized geometries of the ligand and the studied complexes are evaluated by theoretical calculations. The order of complexation energies for the obtained structures is as follows: The redox behavior of repaglinide and metal complexes are studied by cyclic voltammetry revealing irreversible redox processes. The presence of repaglinide in the complexes shifts the reduction potentials of the metal ions towards more negative values.

DOI: 10.15372/JSC20160805