Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

soran2.gif

Baner_Nauka_Sibiri.jpg


Яндекс.Метрика

Array
(
    [SESS_AUTH] => Array
        (
            [POLICY] => Array
                (
                    [SESSION_TIMEOUT] => 24
                    [SESSION_IP_MASK] => 0.0.0.0
                    [MAX_STORE_NUM] => 10
                    [STORE_IP_MASK] => 0.0.0.0
                    [STORE_TIMEOUT] => 525600
                    [CHECKWORD_TIMEOUT] => 525600
                    [PASSWORD_LENGTH] => 6
                    [PASSWORD_UPPERCASE] => N
                    [PASSWORD_LOWERCASE] => N
                    [PASSWORD_DIGITS] => N
                    [PASSWORD_PUNCTUATION] => N
                    [LOGIN_ATTEMPTS] => 0
                    [PASSWORD_REQUIREMENTS] => Пароль должен быть не менее 6 символов длиной.
                )

        )

    [SESS_IP] => 3.91.19.28
    [SESS_TIME] => 1711660884
    [BX_SESSION_SIGN] => 9b3eeb12a31176bf2731c6c072271eb6
    [fixed_session_id] => aea5bad0f3d541154cb6e8d0d5e5dd82
    [UNIQUE_KEY] => 722d5f4f000786a850d50e89d99ba7e9
    [BX_LOGIN_NEED_CAPTCHA_LOGIN] => Array
        (
            [LOGIN] => 
            [POLICY_ATTEMPTS] => 0
        )

)

Поиск по журналу

Журнал структурной химии

2012 год, номер 1

CRYSTAL STRUCTURES OF [Hg(N-ETHYLTHIOUREA)2(CN)2] AND [Hg(N-PROPYLTHIOUREA)2(CN)2]

H. Sadaf1, S. Ahmad1, S. Sharif2, I.U. Khan2, M. Akkurt3, S.W. Ng4, M.I. Khan5, S.A. Bashir5, M. Mufakkar2
1 Department of Chemistry, University of Engineering and Technology
2 Department of Chemistry, Government College University
3 Department of Physics, Faculty of Arts and Sciences, Erciyes University
4 Department of Chemistry, University of Malaya
5 Department of Environmental Sciences, International Islamic University
saeed_a786@hotmail.com
Ключевые слова: mercury(II) cyanide, N-ethylthiourea, N-propylthiourea, X-ray structures
Страницы: 155-159

Аннотация

Two mercury(II) cyanide complexes of N-ethylthiourea (Ettu) and N-propylthiourea (Prtu) ligands, [Hg(Ettu)2(CN)2] (1) and [Hg(Prtu)2(CN)2] (2), were prepared and their crystal structures were determined by X-ray crystallography. In both structures, the mercury atom is coordinated to two sulfur atoms of thioureas and two cyanide carbon atoms in a pseudo-tetrahedral mode with the bond angles in the range of 90.52(11)-162.2(3)°. The structures are stabilized by N-H---S, N-H---N, and C-H---N intramolecular and intermolecular hydrogen bonds.