Crystal structure of bis(iso-maleonitriledithiolate)nickel(II) benzylpiperidinium
Y.-L. Hu, L.-B. Liang, J.-F. Liu, W.-Q. Chen, J.-R. Zhou, X.-P. Liu, L.-M. Yang, C.-L. Ni
South China Agricultural University, 510642 Guangzhou, P. R. China
scauchem534@126.com
Ключевые слова: bis(iso-maleonitriledithiolate)nickel(II) anion, benzylpiperidinium, crystal structure
Страницы: 755-758
Подраздел: КРАТКИЕ СООБЩЕНИЯ
Аннотация
Bis(iso-maleonitriledithiolate)nickel(II) benzylpiperidinium, [BzPid]2[Ni(i-mnt)2] (1) is prepared and characterized by elemental analyses, UV, IR, molar conductivity, and single crystal X-ray diffraction. It is found that 1 crystallizes in the monoclinic space group P21/n with a = 9.551(1) Å, b = 16.520(2) Å, c = 11.004(1) Å, β = 96.60(1)°, V = 1724.6(3) Å3, Z = 2. consolidate the stacking of the molecules The electrostatic interaction between [Ni(i-mnt)2]2– anions and [BzPid]+ cations consolidates the stacking of the molecules.
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