Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

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Яндекс.Метрика

Поиск по журналу

Переход горения в детонацию в бензино-воздушных смесях

2011 год, номер 4

CRYSTAL STRUCTURE AND ACTIVITY OF A NEW Cu(II) COMPLEX WITH O…Cu WEAK INTERACTION


Ключевые слова: Cu(II) complex, structure, square-planar geometry, dimer
Страницы: 802-805

Аннотация

A new CuL2 (HL = α-hydroxyacetophenone) complex is synthesized and investigated by elemental analysis, IR, UV-Vis, and X-ray diffraction. The complex crystallizes in the orthorhombic space group Pbca, a = 14.595(3), b = 12.517(3), c = 15.474(3) Å, V = 2826.88(1) Å3, Z = 4. The title complex has a square-planar geometry around the central Cu2+ ion. Two molecules form a dimer via a weak Cu1…O3 interaction, and the neighboring dimers of molecules are connected into a 2D structure through two very weak C-H¡O interactions. The title complexes has high activity of killing pine wood nematodes.