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Chemistry for Sustainable Development

2022 year, number 6

Studies of the Behavior of Persistent Organic Pollutants in the Baikal-Selenga Ecosystem as an Element of the Implementation of the Stockholm Convention

S. V. MOROZOV1, G. S. SHIRAPOVA2, O. A. ERMOLAEVA1, E. I. CHERNYAK1, N. I. TKACHEVA1, V. B. BATOEV2, D. M. MOGNONOV2
1Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
2Baikal Institute of Nature Management, Siberian Branch of the Russian Academy of Sciences, Ulan-Ude, Russia
Keywords: persistent organic pollutants, gas chromatography-mass spectrometry, chromatographic profiles, bioaccumulative model, environmental risk assessment, Lake Baikal, the Selenga River basin
Pages: 600-611

Abstract

The paper presents the generalizing results of a long-term study (1994-2020) of the behaviour of persistent organic pollutants (POPs) in the unique Baikal-Selenga lake-river ecosystem in Russia and Mongolia. The research started in 1993 on the initiative of V. A. Koptyug by the staff of the Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS and the Baikal Institute of Nature Management SB RAS within the framework of Russian and international field work missions. As a result of the analysis of the data obtained by means of gas chromatography-mass spectrometry, some regularities of the entry, distribution and accumulation of POPs in various regions of the Baikal-Selenga aquatic ecosystem, which is the largest lake-river system in Inner Asia, were revealed. Detailed data on the content, distribution and profiles of organochlorine pesticides, polychlorinated biphenyls and polycyclic aromatic hydrocarbons in surface waters, bottom sediments and biota have been obtained. The studies were carried out over the entire territory of the Baikal-Selenga ecosystem: Lake Baikal, the Selenga River delta, the Selenga River basin at the territories of Russia and Mongolia, including industrial areas and specially protected natural areas. The data obtained are an assessment of the current ecological state of the Baikal-Selenga region and can serve as a basis for identifying anthropogenic impact on the environment and public health with an assessment of environmental risk. These data can be used to develop approaches for environmental quality management and rational use of natural resources, conservation of unique biodiversity and sustainable development of the Baikal region territory and can be considered as an element of the implementation of the Stockholm Convention on POPs.