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Atmospheric and Oceanic Optics

2020 year, number 7

Rotational dependence of line half-width for the fundamental band 00 0 11 - 0 0 001 of CO2 confined in nanoporous aerogel: new measurements

A.A. Solodov1,2, T.M. Petrova1, Yu.N. Ponomarev1, A.M. Solodov1, A.S. Shalygin3
1V.E. Zuev Institute of Atmospheric Optics of Siberian Branch of the Russian Academy of Science, Tomsk, Russia
2National Research Tomsk State University, Tomsk, Russia
3Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
Keywords: CO, аэрогель, Фурье-спектроскопия, aerogel, FTIR spectroscopy

Abstract

The absorption spectra of carbon dioxide confined in aerogel sample with pore sizes of 60 nm have been recorded at a room temperature in the 2250-2400 cm-1 region using a Bruker IFS 125HR FTIR spectrometer. Parameters of spectral lines of CO2 are derived; their dependence on rotational quantum numbers are shown. The results are compared with data available in literature.