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Chemistry for Sustainable Development

2019 year, number 5

Homo- and Copolymerization of Norbornene and Its Derivatives

R. A. RASULOVA, M. D. IBRAGIMOVA, V. S. KADYRLY, E. G. MAKHMUDOVA, M. K. MAMEDOV, K. M. MAMEDOVA, F. S. KERIMOVA
Institute of Petrochemical Processes named after Academician Yu.G. Mamedaliyev Azerbaijan National Academy of Sciences, Baku, Azerbaijan
Keywords: норборнен, гомополимеризация, (мет)акриловые эфиры, (со)полимеризация, катализатор, norbornene, homopolymerization, (meth)acrylic esters, (co)polymerization, catalyst
Pages: 473-480

Abstract

The literature data on the research in the field of homo- and copolymerization of norbornene and its derivatives are discussed in the review. Due to specific structure, norbornene and its derivatives provide the basis to synthesize the polymers and copolymers with various functionalities, differing from each other in the structure and physical-mechanical characteristics of final products. Depending on polymerization conditions, the polymers synthesized on the basis of norbornene are characterized by high optical purity, high thermal and chemical stability, mechanical strength. Copolymers of norbornene with olefins and acrylic monomers combine the properties typical for norbornenes with such characteristics of polyolefins or polyacrylates as high adhesion, elasticity, flexibility of macromolecules, which promotes broadening of their application range. Thus, the availability of the raw material basis of norbornene and its derivatives, together with the unique performance characteristics of the polymers and copolymers based on them, attracts the attention of researches to the studies into the synthesis of new norbornene monomers and the synthesis of polymers and copolymers on their basis for use in various branches of industry. The data presented in the review provide evidence of the promising character of studies in the area of the synthesis of high-molecular compounds with valuable performance characteristics on the basis of norbornene hydrocarbons.

DOI: 10.15372/CSD2019168