S.N. Rychagov, A.V. Sergeeva, O.V. Kravchenko, A.A. Kuzmina
Institute of Volcanology and Seismology, Far Eastern Branch of the Russian Academy of Sciences, Petropavlovsk-Kamchatsky, Russia
Keywords: pore solutions, water extracts, hydrothermal clays, geothermal deposit, alkaline metal-bearing fluid, mineral formation
The main composition of pore solutions of the hydrothermal clays forming extended and powerful thicklayersin on thermal fields of the Pauzhetka geothermal deposit is studied. In vertical cuts of hydrothermal clays two zones differing in physical and chemical characteristics, compositions and conditions of formation of pore solutions are allocated. The crucial role of pH in change of macrocomponent composition of solutions depending on section depth is shown. The conclusion is drawn on formation of pore solutions as a result of direct impact on a matrix of hydrothermal clays of infiltration deep thermal waters, at which there are processes of redistribution of elements between rock and contact solution. Along with the general regularities, essential differences in the conditions of formation of composition of pore solutions on Upper and East Pauzhetsky thermal fields are revealed that is defined by a geological position and the hydrogeochemical regime of concrete sites of the geothermal deposit.
E.V. Deev1,2, V.V. Olenchenko1,2, A.A. Duchkov1,2, A.A. Zaplavnova1, O. V. Safronov1,2 1Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences,Novosibirsk, Russia
2Novosibirsk State University, Novosibirsk, Russia
Keywords: electrical resistivity tomography, active faults, permafrost, Gorny Altai, Lena River delta
Using the example of active faults in the high mountainous part of the Gorny Altai (South Chuya and Kubadu fault zones) and the Lena River delta (Primorsky Fault Zone), active fault zones in the conditions of permafrost development were studied using the electrotomography technique. The method was shown to be effective in identifying active fault zones to depths up to the first hundred metres in permafrost conditions. However, the presence of icy rock with a resistivity greater than 100 kOhm·m limits its application due to the shielding effect of the insulating layer. The main criterion for identifying active faults in geoelectrical sections are subvertical zones of reduced resistivity against a background of high resistivity permafrost layers. This concerns both relatively young seismic ruptures formed during the Chuya earthquake (Ms=7.3) 27.09.2003 in the South Chuya Fault Zone and more aged Holocene fault scarps in the zones of the Kubadru and Primorskiy faults. At the same time, resistivity values in the zones of active faults and seismic ruptures are too high to assume their saturation with free water. The decrease in resistivity in such zones relative to the host permafrost frame may be due to: 1) increased rocks and sediments fracturing; 2) occurrence of thinly fractured material in the core fault zones, including in cracks, where physically bound non-freezing water is concentrated; 3) residual thermal anomalies in the case of modern activations, so that negative temperatures have already been restored, but the process of frozen strata degradation is not fully completed yet; 4) saturation of the geological section with sandy-silty material as a result of the development of liquefaction and fluidization processes during earthquakes. The revealed regularities can be used not only to confirm the zones of morphologically distinctive segments of active faults, but also to search for their buried segments in the areas of permafrost development typical for seismically active high mountain and Arctic regions of Russia and worldwide.
O.V. Nechaev, I.V. Mikhaylov, M.N. Nikitenko, V.N. Glinskikh
1Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
Keywords: transient sounding, electromagnetic monitoring, cryolithozone, geoelectric model, numerical simulation, vector finite element method, Sumudu transform, induction coil, current line, cross-borehole exploration
The article considers the results of mathematical modeling of transient electromagnetic cross-borehole monitoring data for civil and industrial cryolithozone facilities containing thaw zones (taliks) in their vicinity. A solution to the direct problem is presented based on the Sumudu integral transform and the vector finite element method for two types of borehole sources: induction coils and a less common electric current line, taking into account the frequency dispersion of the specific electrical conductivity of permafrost. Numerical three-dimensional modeling of the transient signals is performed in realistic geoelectric models of a gas-producing borehole and a residential building on piles. Based on the modeling results, we revealed the main features and differences of transient cross-borehole monitoring with coils and a line as the source.
N.D. Tolstykh1, M.O. Shapovalova1, V.M. Chubarov2 1V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences,
Novosibirsk, Russia
2Institute of Volcanology and Seismology, Far Eastern Branch of the Russian Academy of Sciences,
Petropavlovsk-Kamchatsky, Russia
Keywords: epithermal deposits, evolution of ore-forming system, enargite, luzonite, famatinite, goldfieldite, fluid acidity, oxidation potential, Kamchatka
Sulfosalts of the tetrahedrite and enargite groups from the epithermal Maletoyvayam Au-Ag deposit were studied by optical and scanning electron microscopy. It was revealed that they crystallized from acid magmatic volcanogenic hydrothermal fluids under conditions of elevated oxygen potential. Early sulfosalts of the pre-gold ore stage of the Maletoyvayam deposit, argentotetrahedrite-(Zn,Fe) and tetrahedrite-(Zn,Fe), associated with pyrite, arsenopyrite and galena, evolved with their enrichment in Te, Se and Cu. An increase in the activity of these elements, which is a consequence of an increase in the oxidation potential of the environment, led to the crystallization of subsequent stibio-, arsenogoldfieldite and enargite group minerals, the excess of Cu in which increased with the evolution of the ore-forming system. Au-bearing minerals are paragenetically related to sulfosalts of the final stage of this evolution. The crystallization trend of sulfosalts (As → Sb → Te) from the Maletoyvayam deposit is also characteristic of other acid-sulfate type deposits, which also include Ozernovskoe and Prasolovskoe, in contrast to the opposite trend (Te → Sb → As), characteristic of sulfosalts from epithermal deposits of the adularia-sericite type of epithermal Au-Ag deposits.
Z. L. Motova1, T. V. Donskaya1, D. P. Gladkochub1, V. B. Khubanov2
a:2:{s:4:"TEXT";s:236:"1Institute of the Earth’s Crust, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia
2Dobretsov Institute of Geology, Siberian Branch of the Russian Academy of Sciences, Ulan-Ude, Russia ";s:4:"TYPE";s:4:"html";}
Keywords: Siberian platform, Middle Paleozoic, carboniferous, terrigenous rocks, petrography, geochemistry, detrital zircons, paleogeodynamics
We presents new data on the
composition and U-Pb (LA-ICP-MS) age of detrital zircons from terrigenous
carboniferous rocks distributed in the southwestern and central parts of the
Siberian Platform cover, which are associated with the finds of diamonds and
their satellite minerals, are presented. The material characteristics and
analysis of minerals of the heavy fraction of terrigenous rocks of the
Baeronovka formation of the carboniferous studied in the southwestern part of
the platform indicate a predominantly acidic composition of rocks in the source
area. The age of detrital zircons from the sandstone of the Baeronovka
formation suggests rocks of the Sayan area of the basement rocks of the
Siberian Platform, namely Paleoproterozoic granitoids and volcanites of the
Southern Siberian postcollisional magmatic belt as the main sources of detrital
material. In smaller quantities, detrital material entered the sedimentation
basin of the Baeronovka formation due to the destruction of Early Paleozoic
rocks of the northern segment of the Central Asian fold belt. The geochemical
characteristics of terrigenous rocks of the Kata formation and Tushama
formation carboniferous studied in the central part of the Siberian platform indicate
an acidic composition of rocks in the area of their source, however, the
mineral compositions of heavy fractions indicate a different composition of
rocks in the source area. The age of detrital zircons from terrigenous rocks of
the Kata and Tushama formations allows us to consider Neoproterozoic
sedimentary rocks and Middle Paleozoic igneous rocks of the Baikal-Patom zone
of the southern Siberian, as well as Middle Paleozoic igneous rocks of the
Vilyui rift and the Yakut diamond-bearing province as the main sources. The
revealed differences in the composition and age of the rocks of the sources of
detrital material for carboniferous sandstones distributed in different areas
of the Siberian Platform confirm the conclusions of the predecessors about the
existence of several local sedimentary basins in the Devonian-Carboniferous in
the inner regions of the platform, the formation of which was preceded by the
Middle Paleozoic tectonic-magmatic activation, accompanied by diamondiferous
lamproite and kimberlite magmatism.
1Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia 2Novosibirsk State University, Novosibirsk, Russia 3Novosibirsk State Technical University, Novosibirsk, Russia 4Institute of Computational Mathematics and Mathematical Geophysics SB RAS,Novosibirsk, Russia
The study compares in detail the signals of an electromagnetic tool with toroidal coils, which were measured in an electrolytic tank with a borehole and numerically calculated in its three-dimensional geoelectric model. For each specific electrical resistivity of the electrolyte, we performed the profiling of the “air-tank” and “tank-borehole” boundaries during the round-trips of the tool. Values of the coupling coefficient of the measured and modeled signals were determined for the entire set of frequencies and positions of the measuring coils in the summary and differential operating modes. We identified a pair of the signals with a virtually constant coupling coefficient at varying electrolyte mineralization. Drawing on this pair, transformations of the tool signals into the apparent electrical resistivities of the medium were constructed. The resulting transformation graphs allow a reliable recalculation of the measured signals of the toroidal tool into the apparent electrical resistivity distribution in the near-wellbore space, which is necessary for the petrophysical interpretation of the field-log data.
A.A. Kirdyashkin1, V.A. Simonov1, A.V. Kotlyarov1, A.V. Jakovlev2 1V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia 2Alfred-Wegener-Institut, Helmholtz Zentrum für Polar- und Meeresforschung, Bremerhaven, Germany
Keywords: Mantle plume, hotspot, asthenospheric free-convective flows, triple junction, mid-oceanic ridge, transform fault, content of rare and rare earth elements, volatile components, melt inclusions, P-wave velocity anomalies
Three mid-oceanic ridges meet in the area of the Bouvet triple junction the Mid-Atlantic, Southwest Indian and American-Antarctic one. At the same time, the triple junction area is characterized by manifestations of magmatism of the Bouvet hotspot. Using available laboratory modeling data, a scheme is presented for the conduit of a thermochemical mantle plume melting from the core-mantle boundary and breaking through to the surface. Using morphobatimetric data for the area of the Bouvet volcanic island, a mass flow rate of magmatic melt for the plume of the Bouvet hotspot was found. Taking into account the melt flow rate, the thermal power of the Bouvet plume source is NB = (1.7–2.0) · 1010 W, and the plume conduit diameter is 9 to16 km. Based on the consideration of the geodynamic regime, the possible evolution of the Bouvet plume is presented. The influence of the geodynamic system of asthenospheric convective flows on the structure of the ocean floor in the Bouvet area is shown. The Bouvet Island was formed under the influence of mantle plume. The Bouvet plume is located in the area of the ascending flow of the asthenospheric rolls and contributes to the roll flow intensification. Transform faults in the Bouvet area were formed under the influence of descending flows of asthenospheric rolls. The width of the trough and the depth of the Bouvet transform fault are determined based on the analysis of the flow structure and heat transfer in the asthenosphere in the Bouvet area. The contribution of the Bouvet plume to the asthenospheric convection roll intensification is also taken into account in our calculations. The conducted geochemical and thermobarogeochemical studies indicate the decisive role of fluid components in magmatic systems of the Bouvet hotspot, which are characterized by enrichment with volatiles (H2, H2O, CO2), alkali (primarily potassium) and lithophilic rare and rare earth elements (La, Ce, Th, Nb, Rb). Taking into account the seismotomographic results, the features of the mantle structure in the triple junction are considered. A high-velocity anomaly is detected along the axial zone of the Bouvet transform fault. The roots of this upper-mantle anomaly can be traced to a depth of 250 km. A low-velocity anomaly has been detected under Bouvet Island. This anomaly can be traced to depths of about 500 km.
I.A. Kozlova, A.K. Yurkov, S.V. Biryulin
Yu.P. Bulashevich Institute of Geophysics, Ural Branch of the Russian Academy of Sciences, Yekaterinburg, Russia
The article presents the possibilities of radon variations application for studying changes in the stress-strain state of rock massif. On the basis of long-term monitoring at the South Kuril geodynamic polygon the methodology of interpretation of volume soil radon activity anomalies is developed. The causal relationship between earthquakes and radon anomalies has been established. It is shown that tectonic events occur after passing the maximum level of the anomaly, and the reflection time depends on the distance between the observation point and the epicenter of the event. The mechanisms of formation of radon anomalies in the zone of compression and extension are proposed.
A.V. Naryzhnova1,2, N.N. Kruk1,2, S.Z. Smirnov1,2,3, Kotler P.D.1,4, A.V. Kulikova4, N.S. Bortnikov5, V.S. Antipin6, E.N. Moroz1, A.S. Volosov1, A.S. Borisenko1 1V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk State University, Novosibirsk, Russia
3Tomsk State University, Tomsk, Russia
4Kazan Federal University, Kazan
5Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry of the Russian Academy of Sciences, Moscow
6Vinogradov Institute of Geochemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia
Keywords: rare metal granites, geochemistry, mineralogy, fluid regime, petrogenesis, Transbaikalia
The paper deals with the age, composition and features of the genesis of granitoids of the Soktuy massif – the petrotype of the Kukulbey complex of Mesozoic rare-metal granites of Transbaikalia. The Soktuy massif is heterogeneous. Several petrographic varieties are distinguished: monzo- granite-leucogranites and microleucogranites of the main intrusive phase, alaskites, alkali-feldspar granite porphyries, granodiorites and quartz syenites of the additional intrusion phase According to the obtained U-Pb-geochronological data, the age of all varieties is indistinguishable taking into account the analytical error and corresponds to the Early Cretaceous. Granitoids differ in a variety of geochemical characteristics: monzo- granite-leucogranites of the main intrusive phase belong to the rare-metal-plumasite type, rocks of the phase of additional intrusions show signs of A-type granitoids. The geochemical and isotopic characteristics of the rocks indicate the participation in their formation of both substrates of the continental crust and deep magmas of mantle genesis. The volatile content in micas and the peculiarities of the composition of inclusions indicate that the formation of magmas occurred with the participation of two types of fluids: chloride and reduced (probably mantle) and more oxidized fluoride (presumably having a lower-crust nature). All melts were generated at depths of no more than 30 km, and the depth of formation of the massif did not exceed 8 km. Based on the obtained data set, a model for the formation of rocks of the massif is proposed.
A.A. Tataurova1, Yu.P. Stefanov1, E.V. Deev1,2 1Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
The junction zones of mountain ranges with sedimentary basins are concentrators of seismogenic faults that develop in settings of regional compression and transpression. The development of two opposing systems of reverse faults and thrusts forms positive (forbergs, “pop-up” structures, fault and tectonic scarps, fault related fold) and negative morphostructures (“pop-down” structures) at the edges of sedimentary basins. As a result, the edges of the basins are involved in uplift. This leads to a gradual growth and expansion of the mountain ranges and a reduction in the areas of intramountain basins, i.e. the reduction mechanism of the upper part of the earth's crust is realized. However, the mechanisms of the emergence of conjugate fault systems are not fully understood. The mechanisms of such deformations in the upper part of the earth's crust were investigated under lateral compression of the rock mass using two-dimensional numerical modeling. The elastic-plastic approximation of the Drucker-Prager-Nikolaevsky model with a non-associated flow law was used. In all models, regardless of the number of layers, reverse faults and thrusts with direct and reverse dips relative to the direction of horizontal compression were formed. As a result, positive and negative structures were formed in the relief of the models, which are analogs of the corresponding natural morphostructures. The obtained results showed that the development and configuration of localized shear bands corresponding to reverse faults and thrusts are influenced by elastic-strength properties, basal friction, and boundary conditions at the lateral boundaries of the model. It has been established that in a multilayer medium a multilayer system of localized shear bands can form because of one stage of deformations that have different slopes and are limited only to a specific layer. Special attention should be paid to models in which interlayer slippage develops. It is caused by different rates of layer displacement relative to each other due to differences in the elastic-strength properties of rocks, which leads to the development of reverse thrusts in the upper part of the section that are not associated with the base of the model. Typically, such thrusts develop in the upper part of the section. Heterogeneities in the base of the models, regardless of strength properties, can affect the spatial localization of localized shear bands that arise at their boundaries. The results of numerical modeling allowed us to better understand the relationship between the mechanical properties of rocks and sediments with the features of the development of reverse-thrust structures.
A.G. Konstantinov 1Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences,Novosibirsk, Russia
Keywords: ammonoids, Ladinian Age, paleobiogeography, Boreal Realm
The study of the spatial distribution of individual groups of marine invertebrates in the geological past and the analysis of the dynamics of their geographical differentiation over time are of great importance both for identifying patters of their evolution and for understanding the history of marine basins. In this work, taking into account modern data on paleontology and biostratigraphy of the Boreal Triassic, the taxonomic composition and distribution of Ladinian ammonoids in different regions of the Boreal Realm are specified. Zonal correlation on ammonoids of the Ladinian deposits of northeastern Asia, British Columbia, Arctic Canada, northern Greenland, Svalbard and Franz Josef Land is carried out, a chronological basis for comparative analysis of coeval ammonoid faunas is obtained. As a result of qualitative and quantitative comparative analysis of ammonoid complexes for different phases of the Ladinian Age, it is established that northeastern Asia was constantly part of the Siberian Province of the Boreal Realm. The separation of the Canadian province of the Boreal Realm occurred at the end of the constantis phase due to the penetration of trachyceratids (genus Protrachyceras) into the paleobasins of Arctic Canada, later, starting from the maclearni phase, its area increased due to the migration of Tethyan forms into the paleobasins of Svalbard. The migrations of trachyceratids, gymnitids and lobitids into boreal paleobasins from the Tethys, as well as boreal tsvetkovitids and nathorstitids into ecotone and Tethyan paleowaters of British Columbia were caused not only by circumpolar currents, but were probably associated with the lifestyle of ammonoids and their habitation in a greater or lesser range of depths of marine basins.
S.Z. Smirnov1, A.A.Kotov2, O.V. Bergal-Kuvikas3,4, A.V. Degterev5 1V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Science, Novosibirsk, Russia 2Graduate School of Environmental Studies, Tohoku University, Sendai, Japan 3Institute of Volcanology and Seismology, Far Eastern Branch of the Russian Academy of Sciences,
Petropavlovsk-Kamchatsky, Russia 4Vitus Bering Kamchatka State University, Petropavlovsk-Kamchatsky, Russia 5Institute of Marine Geology and Geophysics of the Far Eastern Branch of the Russian Academy of Science, Yuzhno-Sakhalinsk, Russia
Keywords: Great Kuril Arc, caldera, volcano, explosive volcanism, magmatism
Caldera-forming explosive volcanism is a most dangerous natural hazard, which have catastrophic consequences to the life, humans and their economic activities. The paper represents a summary of the published and original data on the Late Pleistocene-Holocene caldera-forming volcanism within the Great Kuril Arc (GKA) collected to the recent times. The data available from publications reveal that formation of explosive calderas occurred in all segments of GKA in the Late Pleistocene and Holocene. Most frequent it was in the Southern and Central segments of GKA, where it borders on the back arc basin of Kuril deep-sea depression. The majority of investigated in this study calderas appeared in Late Pleistocene 50-12 Ka and Early Holocene 8-6 Ka. Intensive caldera-forming volcanism in GKA could be contemporaneous to similar volcanism in the East-Kamchatka volcanic belt and Southern Kamchatka. Caldera eruptions of GKA in the Late Pleistocene and Early Holocene were related with evolution of large reservoirs of predominantly dacitic magmas, which were formed due to melting of metabasitic protholiths in the shallow crust (3 – 12 km) at 830 – 890°C. Rhyolitic melts of these magmas were saturated in H2O, CO2, sulfur compounds, and probably by other gaseous species. This caused shallow degassing at the pre-eruptive stages of the magma reservoir evolution. The study rises questions, which solution would provide a basis for more effective prediction of powerful volcanic explosions and monitoring of activity of caldera volcanoes in GKA.
A.F. Khokhryakov, Yu.M. Borzdov, D.V. Nechaev, Yu.N. Palyanov
1V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Science,
Novosibirsk,Russia
Keywords: diamond resorption, mantle metasomatism, oxygen fugacity, HP-HT experiment
Experimental studies on modelling of diamond resorption processes during mantle oxidative metasomatosis in solid-phase matrix in the presence of intergranular fluid have been carried out. The reaction between diamond and periclase with formation of magnesite was realised, which can be considered as a model variant of such reactions as EMOD (enstatite-magnesite/olivine-diamond) or DCDD (dolomite-coesite/diopside-diamond). The studies were performed at a pressure of 6.3 GPa in the temperature range 1100-1400 °C under redox conditions corresponding to the WM (wustite/magnesite) buffer. It was found that the reaction between diamond and periclase to form magnesite occurs only in the presence of 0.5-0.8 wt.% water at temperatures above 1200 °C. The morphology of diamond crystals partially dissolved by intergranular H2O-fluid at fO2 at WM buffer level is typomorphic for diamond dissolution/resorption in water-containing carbonate and carbonate-silicate melts. The main microrelief elements of diamond dissolution shapes are inversely orientated triangular etch pits on relict octahedral faces, shield-shaped or ditrigonal dissolution layers, and drop-shaped hills. The obtained resorption rates at these P-T-fO2 parameters indicate that the absence of diamond or poor diamondiferousness of potentially diamondiferous kimberlite pipes may be due to oxidative metasomatosis in the mantle regions of pipe formation.
N.A. Bushenkova, T.A. Stupina, O.A. Kuchay
Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences,
Novosibirsk, Russia
Keywords: the Okhotsk plate southern boundary, features of the seismic focal zone, lithospheric plate boundary, subduction in the P-wave velocity anomalies field, the seismotectonic deformation main axes directions, Hokkaido, Honshu, Sea of Japan
The study is devoted to determining the position of the southern boundary of the Okhotsk Plate based on the analysis of the seismicity distribution in the area of the Hokkaido, Honshu and adjacent territories according to a local data from Japanese catalogs (JMA) for the period 1998-2022. And comparing them with regional seismic tomography models, as well as with the distributions of the seismotectonic deformations main axes directions according to the focal mechanisms of strong (Mw> 4.7) earthquakes based on the International Seismological Center catalogs data (ISC) for the period 1976-2022 and other relevant geological and geophysical characteristics (gravitational field heterogeneities, crustal thickness, volcanic manifestations, etc.). It was found that the southern boundary of the Okhotsk Plate passes along the southern tip of the Hokkaido Island. Namely through the Oshima Peninsula and Uchiura Bay, and not along the Hidaka Ridge or through Honshu Island, as was assumed in previous constructions by other authors.
A.Sh. Shavekina1, S.B. Bortnikova2, S.S. Volynkin2, N.A. Abrosimova2 1Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia 2V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Science,
Novosibirsk, Russia
Keywords: arsenic, supergene processes, secondary minerals, Khovu-Aksy, mineralogical and geochemical features
The stored waste from processing arsenide Ni-Co ores of the Khovu-Aksy deposit (Republic of Tuva, Russia) is a unique geochemical system in which the joint behavior of As and metals (Fe, Co, Ni, Cu, Zn, Pb) under exogenous conditions can be directly traced. In the course of the study, the mineralogical and geochemical features of arsenic distribution from primary arsenides to newly formed phases and associated metals in waste with a high arsenic content (up to 4%) along the section of trench burial No. 3 were studied. A common characteristic of the entire thickness is a slightly alkaline environment with paste pH = 7.7, Eh 486 mV. Four horizons are distinguished in the section. According to elemental analysis (XRF-SI), accumulation of As, Mo, Pb, Sb, Co and Cu occurs in horizon 2 (80 cm), while Cd, Zn, Ni in horizon 3 (110 cm). In the processed ores, among non-metallic (rock-forming) minerals, quartz, calcite, dolomite, garnet, amphibole-chlorite aggregates, single grains of potassium feldspar (KFS), apatite, barite and muscovite are noted. Arsenic minerals are distributed extremely unevenly across the section, while they are not found in the soil horizon (horizon 4). Arsenic is found in the section in the form of: 1) its own As minerals: safflorite with howuaxite, conichalcite, scorodite, arseniosiderite, sarmientite, gernessite, annabergite, picropharmacolite; 2) isomorphic impurity in secondary formations (iron hydroxides by pyrite, amorphous silica, chloriteThe presence of carbonate minerals in primary ores and the applied technological scheme of ore enrichment with the technology of purifying solutions from arsenic directly affect the secondary mineral association of arsenic minerals.
E.V. Nazarchuk1, Y.G. Tagirova1, D.O. Charkin2, M.G. Krzhizhanovskaya1, A.V. Kasatkin3, S.V. Krivovichev1,4, V.V. Gurzhiy1 1Crystallography Department, Institute of Earth Sciences, St. Petersburg State University, St. Petersburg, Russia
2Department of Chemistry, Moscow State University, Moscow Russia
3Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow Russia
4Nanomaterials Research Centre, Kola Science Centre, Russian Academy of Sciences, Apatity, Russia
mourite, uranyl molybdate, crystal structure, infrared spectroscopy, chemistryA synthetic analog of mourite (SM), (UO2)Mo5O14(OH)4(H2O)2, has been hydrothermally synthesized at 220 ºС and characterized using single-crystal X-ray diffraction, single-crystal and powder X-ray diffraction studies at non-ambient temperatures, X-ray photoelectron spectroscopy, infrared spectroscopy, thermal, and chemical analyses. SM is monoclinic, P2/c, a = 9.9063(6), b = 7.1756(4), c = 12.2105(7) Å, β = 102.496(6)°, V = 847.41(9) Å3; the crystal structure has been refined to R1
= 0.043. The chemical composition of the SM is (the Mo2O5:MoO3 ratio obtained from X-ray photoelectron spectroscopy, H2O by stoichiometry; wt.%): Mo2O5
= 4.61, MoO3 = 61.06, UO3 = 26.95, H2O = 6.76, total 99.38. The empirical formula calculated on the basis of 22 oxygen atoms per formula unit with MoV+MoVI = 5 is (UVI1.03O2)[(MoVI4.63MoV0.37)Σ5.00O13.81(OH)0.19](OH)4(H2O)2. The crystal structure of SM contains UO8, Mo1O6, Mo2O5(H2O), and Mo3O4(OH)2
polyhedra that share vertices and edges to form layers linked by hydrogen bonds only. SM is stable up to 250±10 ºС. Upon heating, continuous dehydration occurs between 160 – 250 ºС until the formation of amorphous products; crystallization above 450 ºС produces UO2MoO4, MoO3, and UMo10O32. Below 250 ºС, thermal expansion of the compound is strongly anisotropic, with the maximal direction perpendicular to the plane of the layers.
The article presents the results of a deep
magnetotelluric survey, conducted for the first time within the Tunka system of
depressions, which belongs to the southwestern flank of the Baikal rift zone.
Despite the fact that the studies were of a regional nature, conductivity
anomalies were identified in virtually all intervals of the geoelectric
section, constructed to depths of 70 km. In the western part of the Tunka rift,
at the level of the lower lithosphere, there is an area of distribution of
rocks presumably heated by a plume, which was identified for the territory of
northern Mongolia according to previous studies. The position of the crustal
conductive layer, probably a mineralized collector of a planetary scale, is
atypical: an increase in its thickness and an uplift of the roof to the central
part of the Tunka depression were established. In the upper part of the earth's
crust, subvertical conductive zones are distinguished, which are traced from
the crustal conductive layer to sedimentary deposits and are associated with
channels of fluid migration of geotherms of mantle genesis. A connection is
noted between these subvertical conductivity anomalies and known outlets of
thermal and/or mineral groundwater - "Nilova Pustyn", "Arshan",
"Zhemchug". In addition, one of the subvertical conductive zones in
the east of the Tunka rift, associated with a channel of fluid migration, is
distinguished in sediments (or does not reach them) in the area of the
village of Tibelti, where the presence of geothermal waters was previously
unknown
A.F. Emanov1, A.A. Emanov1,2, E.V. Shevkunova1, E.A. Gladyshev1 1Altai-Sayan Branch of the Geophysical Survey, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia 2Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
Keywords: Eastern Altai, Tsagan-Shibetu ridge, Tsagan-Shibetu earthquake, aftershocks and foreshocks
The Tsagan-Shibetu earthquake 29.07.2022 with ML = 6.2, MW=5.5, time UTC 13:01:10,1 occurred in the ridge of the same name in the east of the Gornyi Altai near the Tuva Basin (50.51º N, 90.69º E). In the twentieth century, this ridge was seismically inactive and neighbored seismically active ones: the focal area of the Ureg-Nur earthquake of 1970 with MS=7.0 and the seismically active Shapshalsky ridge, where earthquakes with a magnitude of up to five often occurred, and there were no large earthquakes yet. After the Chuya earthquake of 2003 with MS=7.3, significant changes occurred in the seismicity structure of Altai, after a lull, new zones of increased activity emerged, one of which is the Tsagan-Shibetu ridge. In the internal structure of the ridge, a focal area with a triple areal structure and with an impulse development of the process over time was formed. The formation of high ridge activity occurred in the presence of foreshocks.
1 Institute of Geochemistry named after. A.P. Vinogradov Siberian Branch of the Russian Academy of Sciences (IGC SB RAS), Irkutsk, Russia. 2North-Eastern Research Institute n.a. N.A. Shilo Far Eastern Branch of the Russian Academy of Sciences (NEISRI FEB RAS), Magadan, Russia. 3Institute of Natural Resources, Ecology and Cryology, Siberian Branch of the Russian Academy of Sciences (INREC SB RAS), Chita, Russia. 4 Irkutsk Research Institute of Rare and Precious Metals and Diamonds (RI AO Irgiredmet), Irkutsk, Russia.
Keywords: gold ore deposits, mineralogical-geochemical and mineralogical-technological characteristics of ores, zoning, ore-magmatic system, Aliinsky ore cluster, Transbaikalia, Mongol-Okhotsk orogenic belt.Title
The article presents new data on the structural position, mineralogy and geochemistry of ores for the Aliinsky ore cluster and their technological features. The mineralogical and geochemical zoning of the Verkhne-Aliinsky gold ore deposit and the entire Aliinsky ore cluster as a whole is characterized The subordination of local and horizontal zoning of mineralization within the node, localization of granitoids of the late phase of the Late Jurassic Akatuevsky complex is shown. A conclusion was made about the connection of mineralization with granitoids within the framework of a single ore-magmatic system that existed in unstable P-T-X conditions of shallow depths, transitional to near-surface. This distinguishes the Verkhne-Aliinskoye deposit from the Sredne-Golgotayskoye and Sosnovskoye deposits that are similar in composition and determined, partly, the technological resistance of its ores.
N.O. Kozhevnikov1
Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences,
Novosibirsk, Russia
Keywords: interfacial polarization, the Maxwell-Wagner effect, voltage source, current source, induced polarization and time domain electromagnetic prospecting methods
The article, by the example of a layered model which can be reduced to the equivalent two-layer one illustrates the differences in the frequency and transient responses of interfacial polarization depending on which source – current or voltage – is used to excite the ground in electrical and EM geophysical prospecting methods. In materials science, a voltage source is usually used to study interfacial polarization. In this case, the manifestations of interfacial polarization are known as the Maxwell-Wagner effect. As for the geophysical induced polarization method, it uses a current source to energize the ground, which causes frequency and transient responses of the interface polarization to differ from those predicted by the Maxwell-Wagner theory. In principle, using the interface polarization frequency or transient responses measured with both current and voltage sources, one can find all parameters of the equivalent two-layered model. Unfortunately, polarization of grounding electrodes complicates in-situ studies of the Maxwell-Wagner effect using a grounded source. There is no such a problem in the time domain electromagnetic prospecting method: when the current in the transmitter loop is switched off, a vortex electric field is induced in the ground, which – in terms of the circuit theory – is equivalent to using the voltage source.
V.A. Vanin1,2, A.M. Mazukabzov1, A.E. Budyak2,3 1Institute of the Earth's Crust SB RAS, Irkutsk, Russia 2Irkutsk National Research Technical University, Irkutsk, Russia 3Vinogradov Institute of Geochemistry, Russian Academy of Science, Siberian Branch, Irkutsk, Russia
Keywords: Sukhoi Log deposit, layering, axial-plane cleavage, foliation, linearity, buckling fold, laminar current
The article presents several published opposing points of view on the ore-controlling stage of the large (⁓ 2,000 t) Sukhoi Log gold deposit, as well as data from a detailed geological and structural analysis obtained by the authors. The deposit is located in the southern framing of the Siberian Craton in the black shale deposits of the Khomolkhin suite (610-600 Ma) on the territory of the Baikal-Patom folded belt. The complex regional structure of the Baikal-Patom belt formed as a result of the addition of the Baikal-Muya belt to the Siberian craton is demonstrated. The formation of industrial ores of the Sukhoi Log deposit and ore-controlling folding occurred in the Late Ordovician – Early Silurian (~ 450–420 Ma). The second stage of formation of weakly gold-bearing ores occurred in the early Carboniferous (340‒330 Ma). As a result of the conducted study, the absence of an ore-controlling fault zone of the syn-folded stage (450‒420 Ma) was established. It is shown that the internal structure of the gold ore zone is represented by intensively deformed rocks in the anticline core, where gold-quartz-pyrite veins occur in layers. It is concluded that the Sukhoi Log deposit is a classic example of disharmonious crumpling of plastic rocks in the core of an anticline, where signs of two stages of structure formation are combined: the longitudinal bending of a rock mass with the flow of matter and its (matter) laminar flow. Geological and structural studies of the deposit, together with previously published data, allow us to classify the deposit as an orogenic type, with a metamorphogenic-metasomatic of the redistribution of ore matter.
Yu.P. Ampilov1,2, S.V. Gorbachev1 1Lomonosov Moscow State University, Moscow, Russia 2Oil and Gas Research Institute of the Russian Academy of Sciences, Moscow, Russia
Keywords: seismic monitoring, field development, 4D seismic survey, towed streamers, seafloor stations, reservoir pressure, reservoir flooding, fiber optic systems, seismic inversion, acoustic impedance
4D seismic exploration is a series of consecutive time-separated 3D areal seismic surveys at oil and gas fields under development. Its purpose is to attempt to register changes in productive formations caused by hydrocarbon extraction from the subsoil in the seismic wave field and, on this basis, optimize the scheme for further field development.
This article provides the first comprehensive analysis of the current state of 4D seismic exploration in Russia. Unfortunately, there are only a few cases of using this technology, while global experience already includes hundreds of successful examples. Various options for its implementation at sea and on land are considered. Almost all known cases of 4D seismic exploration application in Russia, which are still few, are given and the future prospects of this method are analyzed.
M.F. Erbajeva1, S.A. Reshetova2,3, B.B. Karasev4, and N.V. Alexeeva1 1Dobretsov Geological Institute, Siberian Branch of the Russian Academy of Sciences, Ulan-Ude, Russia 2Vinogradov Institute of Geochemistry, Siberian Branch of the Russian, Irkutsk, Russia 3Institute of Natural Resources, Ecology and Cryology, Siberian Branch of the Russian Academy of Sciences, Chita, Russia 4A.P. Karpinsky Russian Geological Research Institute, St. Petersburg, Russia
Keywords: biostratigraphy, small mammals, paleovegetation, Late Pleistocene, Eastern Transbaikalia
The current paper presents the results of multidisciplinary studies of the Late Pleistocene deposits exposed at the Nozhyi site of the Eastern Transbaikalia. New data on small mammals have filled gap in the fossil records of the Late Pleistocene faunas of the region. Faunal remains and spore-pollen samples were derived from loessial deposits rare distributed in the region. The rich faunal association and data on paleoflora of one cold stage of the Late Pleistocene were found in the section. The fauna is dominated by taxa inhabited the open steppe landscapes: Ochotona daurica, Marmota sibirica, Lasiopodomys brandti, Cricetulus barabensis and Allactaga saltator. The faunal species composition and the quantitative relationships of taxa as well as the evidence on palaeoflora demonstrate the paleolandscapes around Nozhyi site. Widely distributed forest steppes with open steppe landscapes, herbage meadow and territories with sandy desert were reconstructed for studied faunal locality.
E.Yu. Golubkova1,*, E.A. Kushim1, E.G. Raevskaya2, I.M. Bobrovskiy3, T.S. Zaitseva1, E.G. Dovzhikova4, A.V. Titova1, A.V. Kolesnikov5, D.V. Grazhdankin6 1 Institute of Precambrian Geology and Geochronology, Russian Academy of Sciences, St. Petersburg, Russia 2 A.P. Karpinsky Russian Geological Research Institute, St. Petersburg, Russia 3 Helmholtz-Zentrum Potsdam Deutsches GeoForschungsZentrum, Potsdam, Germany 4 Ukhta State Technical University, Ukhta, Russia 5 Geological Institute, Russian Academy of Sciences, Moscow, Russia 6 Trofimuk Institute of Petroleum Geology and Geophysics, Novosibirsk, Russia
Keywords: Microfossils, macrofossils, glauconite, Rb–Sr dating, stratigraphy, Vendian, Ediacaran, Cambrian, East European Platform
We carried out paleontological studies of the Vendian–Cambrian boundary strata from the Leningrad Region in the north of the East European Platform (northern part of the Baltic Basin). A stratigraphic succession of micro- and macrofossil associations has been recognized in the section of the Taitsy-2 drillcore comprising three Upper Vendian associations: (I) Aataenia reticularis, (II) Vendotaenia antiqua – Incertae sedis Forma 1, and (III) Bicuspidata fusiformis – Vanavarataenia insolita of the Kotlin Regional Stage; and two Lower Cambrian associations: (IV) Ceratophyton sp. – Teophipolia lacerate of the combined Rivne–Lontova Regional Stage, and (V) Archaeodiscina umbonulata – Globosphaeridium cerinum – Skiagia orbiculare of the Dominopole Regional Stage. The early Cambrian taxa Ceratophyton sp., Granomarginata squamacea, Teophipolia lacerata, and Platysolenites antiquissimus first appearing at the base of the Lomonosov Formation and extending into the overlying Siverskaya Formation define the position of Precambrian–Cambrian boundary. The Rivne and Lontova regional stages are indistinguishable based on palaeontological data. The co-occurrence of fragmented Metazoan fossils and acanthomorphic acritarchs in the Lyukati Formation expands the palaeontological characteristics of the Dominopole Regional Stage of the European part of Russia. We also conducted isotope-geochronological studies of sandstone-hosted glauconite from the Lower Cambrian Siverskaya Formation that yielded a Rb–Sr date of 457 ± 3 Ma. The glauconite appears to be altered and rejuvenated as suggested by mineralogy and crystallochemistry data, is not suitable for stratigraphic purposes, but provides information on timing and contribution of later geological processes.
V.I. Dzhurik, E.V. Bryzhak, S.P. Serebrennikov, A.N. Shagun, A.Yu. Eskin
Institute of the Earth`s Crust of the Siberian Branch of the Russian Academy of Sciences, Russia, Irkutsk
Keywords: seismic effects, Baikal coast, initial seismicity, earthquakes, seismic microzoning, accelerograms, frequency characteristics, spectra, accelerations, resonant frequencies
Using a complex of geophysical, seismotectonic and engineering-seismological studies and the proposed methodological approaches, an assessment of seismic effects at various levels of seismic hazard zoning of the Central Baikal territories is given. The implemented approaches are substantiated by identifying zones of probable occurrence of large earthquakes and specifying their main indicators necessary for the most justified assignment of initial signals corresponding to the parameters of predicted large earthquakes. The basis for the reliability of the selected approaches and methods, in relation to specifying the initial seismicity, are the manifestations of previously registered relatively large earthquakes in the studied territory and, in the direction of seismic hazard zoning of specific territories on a probabilistic basis, the registered data on the behavior of coastal water-saturated massifs of loose sediments according to local earthquake records are quite reasonably accepted. The implemented approaches using a set of geophysical methods in the studied areas allow improving the methods of forecasting maximum seismic impacts for different soil conditions in order to obtain a set of seismic characteristics for them in the form of accelerograms, acceleration spectra, frequency curves and their parameters required for designing earthquake-resistant structures in the coastal areas of Lake Baikal. The studies carried out in this direction are presented using the example of a site located within the seismically active southeastern part of Central Baikal and on the worst soil conditions in relation to the manifestation of seismicity in its coastal areas.
V.V. Shcherbakova1, A.M. Pasenko2, V.P. Shcherbakov1, G.V. Zhidkov1, N. A. Afinogenova1, A.A. Karimov3 1 Borok Geophysical Observatory, department of Schmidt Institute of Physics of the Earth, Russian Academy of Sciences, Yaroslavl obl., pos. Borok, Russia 2О.Yu. Schmidt United Institute of the Physics of the Earth, Russian Academy of Sciences, Moscow, Russia 3Institute of the Earth’s Crust, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia
Keywords: Proterozoic. bimodal mode of geomagnetic field generation, low paleointensity, Proterozoic, Thellier-Coe and Wilson-Burakov methods, Anabar Uplift, Siberian Platform
Paleointensity determinations of the geomagnetic field in the Proterozoic were performed on a collection of rocks selected from intrusive bodies in the northern part of the Siberian Platform, with an age of approximately ≈ 1500 Ma. The magnetic and thermomagnetic properties of the rocks have been studied in detail, and X-ray diffraction and electron microscopic studies have been performed. It has been shown that the carriers of the characteristic component of the natural remanent magnetization are single- and small pseudo-single-domain magnetite grains. The paleointensity Banc was determined using the Thellier-Coe method with the check-points procedure and the Wilson-Burakov method. For six sites, 22 (34 with doubles) determinations were obtained that meet modern reliability criteria. All of them show low values of the field strength and virtual dipole moment, varying within the range (4.7–17.6) μT and (1.21–3.85)×1022 Am2, respectively, which is about four times lower than their
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average values in the modern epoch. A joint analysis of the paleointensity determinations for the Proterozoic presented in the world paleointensity database and the inclination function a(I) = 1/[1+3cos2(I)]½ was performed. It is shown that the data in the diagram (Banc vs a(I)) fall into two clusters of high and low paleointensity values. At the same time, both clusters testify to the dipole geometry of the field, independent of its intensity. The performed analysis confirms the hypothesis of a bimodal mode of geomagnetic field generation in the Proterozoic, which may indicate the absence of a solid inner core in the Early and Middle Proterozoic, attributing its nucleation to a later time (Ediacaran).
I.V. Karmysheva, V.A. Yakovlev, S.N. Rudnev, E.D. Zyukov, D.V. Semenova
V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
Keywords: Magmatic enclaves, xenolith, I-granite, U-Pb dating, Sm-Nd isotope geochemistry, Kaakhem batholith
The article presents the results of isotopic, geochronological, geochemical and mineralogical studies, as well as mineral composition analyses of melanocratic enclaves within the granites of the Sarkhoy complex (Kaakhem magmatic area, Eastern Tuva). According to geochronological data (zircon, U-Pb), the age of the enclaves differs from that of the host granites (480 MA and 450 MA, respectively). The εNd(T) values for the enclaves are +3.2, while for the Sarkhoy complex granites, εNd(T) ranges from 0.5 to 1.7. This suggests that the enclaves cannot be considered cumulates from an earlier phase of granite melt crystallization or restites of the Sarkhoy complex granitoid protolith. Melanocratic enclaves represent xenoliths that, based on their age and isotopic characteristics, can be attributed to the early phase of the diorite-tonalite-plagiogranite association of the Early Tannuola complex. Entrapment of fragments of mafic rocks occurred during the ascent of the granitic melt (~450 million years ago) at the middle crustal level (T ~ 700°C, P = 1.9–2.5 kbar), leading to their partial assimilation and compositional alteration through interaction with the felsic melt.The presence of xenogenic zircon in the Sarkhoy complex granites, with an age of 480 million years, comparable to the age of the xenoliths, suggests a possible contribution of Early Ordovician complexes to the formation of a significant volume of magmatic melt in later stages of regional evolution. Xenoliths of basic rocks in the granitoids of the Sarkhoy complex, studied in the eastern part of the Kaakhem area, represent products of melting of the primitive mantle, which fundamentally distinguishes them from the coeval gabbroic complexes of the western part of the area.
N.A. Bushenkova, O.A. Kuchay
Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
Keywords: strongest crustal earthquakes, aftershock and background seismicity, scalar seismic moment, P-wave velocity anomalies field, Central Asian region
The distribution of more than three dozen strongest intraplate crustal earthquakes (with Mw ≥ 6.9) recorded in Central Asia (20° - 55° N, 55° - 120° E) for the 1971-2022 is considered, including the level of their aftershock activity and background seismicity in the field of velocity inhomogeneities of the medium. The analysis of background and aftershock seismicity with mb(isc) ≥ 4.5 (from http://www.isc.ac.uk) was analyzed at the locations of focal zones (3°×3°). Within such zones, the total scalar seismic moment of background seismicity and aftershock sequences were calculated. Background seismicity was estimated for a 50-year time period before and after the main earthquake and its aftershocks. The duration of repeated shocks series is limited to one year. Against the background of the generalized seismotomographic model of Asia (at a depth of ~50 km), crustal foci of 24 strong earthquakes mainly seek toward zones of sign changes in P-wave velocity anomalies, three earthquakes are recorded in the low velocity zones and 4 in the high velocity zones. The largest values of the total scalar seismic moments released during the implementation of background seismicity are located within the negative P-wave velocities anomalies, as well as along the boundaries of sign changes in anomalies. When scalar seismic moments are released during aftershock and background activity, as well as the main event, the prevailing values remain within e+27. Increased values (e+28) are typical for zones of anomalies sign change and the area of positive anomalies of P-wave velocity. Low values of total scalar seismic moments of background and aftershock events are observed in the focal zone of six sites (3°×3°). It has been suggested that the maximum magnitude for the 100-year period (1901-2022) was realized in these zones and the release of accumulated stresses could be carried out exactly through the strongest earthquakes.
Uniaxially compressed granites were subjected to orthogonally directed pointed impact damaging. The shock-induced acoustic emission (AE) was detected by a highly sensitive wide-band piezo-transducer made of PZT ceramics. The AE time series were analyzed in the frequency ranges of 80–200 кГц (conditionally low-frequency zone) and of 300–500 кГц (high-frequency zone). The energy distributions in AE pulses detected in the lower frequency range followed a power law specific to the cooperative microcracking process, while the distributions recorded in the higher frequency zone exhibited an exponential (Poisson-like) function distinctive to random, non-interacting AE-events. The microcrack accumulation in the low-frequency zone was characterized by the b-value based on the Gutenberg-Richter law. At constant impact energy, the b-value grew progressively with the increase of the uniaxial compression of samples from zero to the highest nondestructive value thus indicating the decrease of the contribution of larger cracks. At the compression close to (but not reaching) the ultimate strength, an impact action caused the subthreshold fragmentation (trigger failure) of granite.
Last decades it has been shown that additional information about the structure and composition of rocks can be extracted from time domain induced polarization (IP) studying the transient characteristics of IP in a large time range from 1 ms to 10 s or more. In this paper compare field IP data obtained on the Yasnoe gold deposit (Taimyr Peninsula) with laboratory IP measurements on 37 rock samples from the same deposit. The samples differed in composition, degree of alteration, type of electron-conductive minerals (pyrite, graphite) and their distribution in the rock. For representative samples of the collection mineralogical and micro-computed X-ray tomography (μ-CT) studies were conducted. This allowed to determine the features of the mineral composition and structure of the samples, as well as to obtain a quantitative characteristic of electron-conductive minerals (pyrite and graphite). According to field and laboratory IP data the relaxation time distributions (RTD) have a similar shape for the same types of rocks. Based on the μ-CT data and the Maxwell-Garnett model, the RTD of the samples were calculated. For some of samples found a good agreement between the CT-based and the IP-based RTD. For others to obtain a satisfactory agreement between the CT-based and IP-based RTD it is necessary to assume that a certain number of pyrite inclusions are passivated or have a flattened shape. The revealed contradiction can be explained by the limited applicability of granular models for well-cemented, low-porosity rocks. This demonstrates the necessity to create an IP model of the rock with the inclusions of electron-conductive minerals that incorporates the structural features of low-permeability capillary media.
V.S. Sobolev Institute of Geology and Mineralogy Siberian Branch Russian Academy of Sciences, Novosibirsk, Russia
Keywords: mantle, fluid, mantle metasomatism, subduction, deep volatile cycle
At pressures of 3.0 and 5.5 GPa and a temperature of 1200°C, metasomatic reactions involving garnet lherzolite and SiO2-, Al2O3-, and alkali-rich supercritical fluids or melts have been experimentally studied. These fluids and melts could potentially be formed during the processes of dehydration, decarbonation, and melting of metasediments in subduction zones. The reaction of garnet lherzolite with model subduction mobile phase has been shown to lead to changes characteristic of modal metasomatism in the lithospheric mantle. As a result of the reaction with the melt at a pressure of 5.5 GPa, phlogopite-bearing garnet lherzolite is formed, while at a pressure of 3.0 GPa, phlogopite-bearing garnet harzburgite is produced. With an increase in the volatile content, primarily CO2, in the fluid/melt at pressures of 3.0 and 5.5 GPa, the reaction proceeds through intense carbonation of peridotite, leading to the disappearance of olivine and the formation of orthopyroxene and magnesite, resulting in the transformation of lherzolite into carbonated pyroxenite. At a pressure of 3.0 GPa and a temperature of 1200 °C, a carbonate-silicate melt rich in alkalis is formed. Overall, the presence of a significant amount of dissolved CO2
in a SiO2-rich fluid or melt induces metasomatic transformations in peridotite that are very similar to those occurring during its reaction with carbonatite melts. Specifically, at a molar ratio of CO2/(CO2+H2O) < 0.23, phlogopite is formed, while at >0.51, magnesite is produced. Phlogopite and magnesite do not form simultaneously in the products of metasomatic reactions.
Z. A. Tembotov1,4, N. A. Malyshev2, V. E. Verzhbitsky2, A. A. Borodulin2, V. V. Obmetko2, D. K. Komissarov2, A. A. Kolyubakin3, A. V. Stupakova4, M. A. Bolshakova4, A. A. Suslova4, A. G. Kalmykov4, N. V. Pronina4, E. A. Krasnova4,5, R. M. Gilaev4, A. V. Mordasova4, I. V. Kuvinov4 Arctic Scientific Center LLC, Moscow, Russia
2Rosneft Oil Company, Moscow, Russia
3LLC "RN-Exploration", Moscow, Russia
4Lomonosov Moscow State University, Moscow, Russia
5Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow, Russia
Keywords: stratigraphic drilling, new wells in the Arctic, Laptev Sea basin, source rock, generation potential, organic matter, maturity
The Laptev Sea sedimentary basin is located in the eastern part of the Russian Arctic shelf and has been fairly well studied by geophysical methods, but until recently, drilling data were lacking. In 2021, six new stratigraphic wells were drilled on the Laptev Sea shelf north of the Anzhu Islands by order of PJSC NK Rosneft. As a result, unique core material was obtained, which was studied using a wide range of analytical methods. This article is devoted to the analysis of the geochemical characteristics of the oil and gas source rocks (OGSR) of the Cretaceous-Cenozoic complex, which in the Laptev Sea basin can be considered as a potential for hydrocarbon generation. The paper presents the main pyrolysis parameters characterizing the proportion of free hydrocarbons in the rock (S1), oil generation potential (S2), maturity (Tmax), as well as the maceral composition of rocks and vitrinite reflectance (VR). As a result, it was established that carbonaceous and clayey-siltstone rocks of the Paleocene-Eocene complex are enriched in organic matter (OM) containing up to 20% of the lipid component and are capable of independently generating not only gaseous but also liquid hydrocarbons. Unlike the OM of the rocks of the Paleocene-Eocene complex, the OM of the Lower Cretaceous strata is at a much higher stage of transformation, which corresponds to the peak of the "oil window" and the beginning of the main phase of gas formation MK2-MK4. The accumulation of OM occurred in various lithofacies conditions; both humic type III kerogen and mixed type II-III kerogen are found in the rocks. Based on the drilling results and studies conducted in the section of the sedimentary cover of the aquatic part of the Laptev Sea, factual data on the characteristics of oil and gas source rocks were obtained for the first time, which can be used to predict the oil and gas potential of both the Laptev Sea basin and the entire East Arctic region.
The brine and long drilling core (4.8 m) of bottom sediments of the hyperhaline Maloye Yarovoe Lake were studied. For the first time, the detailed chemical composition of pore waters and microbial diversity of bottom sediments were studied along the section. A complex mineral composition of sediments was revealed, reflecting the evolution of salinity and changes in sedimentation conditions in the Holocene. In the upper horizons, the mineral composition of the sediment is dominated by halite, quartz, and plagioclase, while in the chemical composition, Na and terrigenous elements (Si, Al, Fe, K) are associated with greater salinity and a high level of lake waters, while in the lower intervals, an increase in gypsum, calcite, magnesite, as well as Ca, Mg, Sr, U, Stotal, S (VI) is noted, which indicates a drop in salinity and the level of lake waters in the past. Authigenic minerals (pyrite, hydrotroilite, siderite, ankerite) are formed in reducing environmental conditions, in the process of bacterial sulfate reduction. Distribution of biogenic elements along the section is stratified: maximum TOC (up to 3.2%) and TN (up to 0.52%) in the upper sediment layers is associated with accumulation of OM of planktonic genesis, and a decrease with depth reflects destruction of OM during diagenesis and changes in the bioproductivity of the lake. In pore waters, in comparison with brine, an increase in the average contents of ions SO42–, PO43–, Ca2+ and dissolved elements — Si, Al, Fe, Mn, Mo — is noted. A trend is observed for a decrease in Cl–
concentrations with depth and an increase HCO3–, Ca2+, Sr2+, and Mn2+ in pore waters, which indicates some decrease in the salinity of lake waters and more intense processes of carbonate sedimentation.. Cyanobacterial mats play an important role in the biogeochemical cycles of the lake, they accumulate Zn, S and Mg in their composition, and their microbial communities (Pseudomonadota, Cyanobacteriota, Rhodothermota) create unique conditions for the formation of zinc sulfides, copper carbonates, as well as sulfides and intermetallics of noble metals (Ag-Au). Microbial processes play a key role in the formation of authigenic minerals and the destruction of organic matter during diagenesis.
Based on new sedimentological, lithochemical, and biostratigraphic data, the main part of the Inikan Formation, which is part of the Kuonamsky Complex of the Lower and Middle Cambrian on the Siberian Platform, has been characterized. Using an integrated approach, including textural analysis, study of the geochemistry of rock-forming oxides and organic carbon, lithochemical calculations, optical petrographic, and X-ray structural studies, a classification of carbonaceous rocks in the Inikan and Chay Formations has been proposed. This has allowed us to clarify the structure of the overall section and the conditions under which Cambrian deposits formed. For the first time, widespread influence of volcanic activity during sedimentation in the Kuonamsky Complex in the southeastern Siberian Platform has been identified. The distribution of paleoseismic breccia in the section has also been described, with horizons that represent good regional stratigraphic markers. Limitations in the use of the Strakhov module and the Nesbit-Young CIA index for characterizing sedimentation conditions of domanicoids have been revealed.
V.B. Bazarova, M.A. Klimin, M.S. Lyashchevskaya, E.N. Zakharchenko, T.R. Makarova 1Pacific Institute of Geography, Far Eastern Branch of the Russian Academy of Sciences, Vladivostok, Russia 2Institute of Water and Environmental Problems, Far Eastern Branch of the Russian Academy of Sciences, Khabarovsk, Russia
Keywords: peat deposits, botanical composition, diatoms, spores and pollen, photosynthetic pigments, peat ash content, moisture index, radiocarbon dating, Far East of Russia
A continuous record of paleogeographic events of the Holocene has been reconstructed based on biostratigraphic study and radiocarbon dating of the coastal peat bog in Nerpichy Bay, Sea of Okhotsk. Development of zonal landscapes since the end of the Late Pleistocene began from shrub forest-tundra to birch elfin forest with the first manifestations of broad-leaved trees in the early Holocene, dominance of dark coniferous taiga with maximum participation of broad-leaved trees in the middle Holocene, their further reduction in the late Holocena and almost complete disappearance in our time. On the coast peat accumulation began with an increase in temperatures about 10.2 ka cal. BP. A feature of the bog ecosystem development was the rapid change of the swampy larch forest after large-scale fires to a community dominated by green mosses, and then to shrub-grass-sphagnum phytocenoses. Further successions occurred with a gradual replacement of eutrophic-mesotrophic sphagnum mosses by oligotrophic Sphagnum fuscum, for which the highest rates of peat accumulation were noted 7.2-6.1 ka cal. BP. In this time the average annual temperature was approximately 2° C higher than today, and the long-term average annual precipitation was approximately 40 mm higher than at present. The most pronounced cooling periods in the Holocene occurred 10.6-10.2, 9.2-8.9, 8.3-8.0, 5.2-4.8, 4.3-4.0, 3.5-3.3, 2.8-2.5, 1.5-1.0 and 0.6-0.4 ka cal. BP. The cooling events identified in the southwestern Priokhotye region are consistent with the sequence of cold events of the Holocene both in the region and in the Northern Hemisphere.
The taxonomic composition of acritarchs from Albian-Cenomanian deposits recovered by boreholes in the southwest of Western Siberia has been studied. Two new genera and species of acritarchs have been described monographically: Pyramidinium annulatum gen. et sp. nov. and Trilobatina angusta gen. et sp. nov. The species P. annulatum is found both in the Albian, Khanty-Mansiysk Formation, and in the Cenomanian, lower part of the Uvat Formation. The second species T. angusta are found only in the Cenomanian, Uvat Formation.
A.M. Fedorov 1, G.A. Yurgenson 2, A.I., Nepomnyashchikh 1, A.P. Zhaboedov 1, M.D. Zimin 1, Z.I. Kulikova 1, V.A. Makrygina 1, O.I. Chachanagova 1, D.TS. Aurzhanaeva 1A.P. Vinogradov Institute of Geochemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia.
2Institute of Natural Resources, Ecology and Cryology, Siberian Branch of the Russian Academy of Sciences, Chita, Russia. 3 N.L. Dobretsov Geological Institute, Siberian Branch of the Russian Academy of Sciences, Ulan-Ude, Russia
Keywords: Transbaikalia, Borshchovichny Ridge, quartz veins, quartzites, geochemistry, fluid inclusions, oxygen isotopes
Quartz veins and quartzites of the Unda quartz vein zone (southern part of the Borshchovochny Ridge) of the Argun block of the Mongol-Okhotsk fold belt have been studied using modern high-precision methods. The first detailed characteristics of mineralogical, petrographic and geochemical features of quartz of the Unda zone is given. Samples of vein quartz and quartzites taken at the tectonic contact between the igneous Middle-Late Jurassic granitoids of the Borshchovoсhny complex and overlying volcanogenic-sedimentary rocks of the accretionary complex of the Middle Jurassic age (Talangui Formation) are intensely deformed and mylonitized. Another part of quartz veins formed in metamorphic rocks located at a distance from the tectonized zone (Dzhidinsky section) are weakly granulated. The parameters of fluid inclusions in vein quartz in the Borshchovochny and Talangui sections were determined. Quartz veins and quartzites are genetically related to the host rocks and inherit their geochemical and isotopic features. As a result of deformation processes, the content and ratio of impurity elements in quartz veins and quartzites decreases and changes.
S.V. Borzenko, I.A. Komogortseva
Institute of Natural Resources, Ecology and Cryology, Siberian Branch of the Russian Academy of Sciences (INREC SB RAS), Chita, Russia.
Keywords: lakes, sulfates, sulfate reduction, evaporation, interaction of water with rock
This study analyzes the mineral and chemical composition of water and sediment, as well as the isotopic compositions of water, carbon, and oxygen in dissolved and precipitated carbonates, sulfate sulfur, and hydrogen sulfide. It has been established that the groundwater and surface water supplying saline sulfate lakes belong to the sulfate-bicarbonate geochemical type with a pH of less than 9. The research indicates that the region predominantly features soda and sulfate types of saline lakes. It has been revealed that in these types of lakes, the sulfate coefficient of the water exceeds 1, while the value of this coefficient decreases with increasing salinity due to the precipitation of thenardite and the process of sulfate reduction. It has been demonstrated that changes in the hydrochemical types of lakes lead to alterations in the mineral composition of their bottom sediments. During low-water periods, autochthonous sediment accumulation predominates, with an increased proportion of dolomite and clay minerals such as kaolinite and hydromica, while montmorillonite is additionally prominent in soda lakes. Concurrently, isotopically heavy oxygen accumulates in carbonates. Further increases in water salinity are accompanied by the precipitation of gelyusite, trona, and anhydrite, as well as a transition from soda to sulfate types. The formation of thenardite results in a shift from the sulfate to the chloride type. During the period of lake desalinization, allochthonous sedimentogenesis prevails, leading to the accumulation of clastic material in lake sediments, primarily represented by plagioclases and feldspars, alongside carbonates with an isotopically lighter composition of oxygen in the carbonates.
1Institute for Complex Analysis of Regional Problems, Far Eastern Branch of the Russian Academy of Sciences, Birobidzhan,Russia
2Hydrogeological service of JSC "Belokurikha Resort", Belokurikha, Russia
Keywords: organic matter, thermal waters, genesis, bacterial activity, hydrocarbons
The present study is aimed at the determination of organic compounds in thermal waters of the Belokurikha deposit (Altai Territory), which is important both for balneology and regional ecology. The TOC concentration ranges from 0.42 to 0.55 mg/L. Using capillary gas chromatography-mass spectrometry and solid phase extraction, 69 organic compounds were identified, forming 16 homologous series. Normal and iso-alkanes (25 %), as well as carboxylic acids and their esters (24 %) and aromatic hydrocarbons (14 %) dominate in thermal waters. The molecular weight distribution of the limiting hydrocarbons (odd/even1.3–1.5, ACL 16.6–17.5) and the presence of characteristic compounds indicate that the organic matter in the waters studied is of autochthonous, predominantly bacterial origin. A number of identified constituents may indicate a low level of anthropogenic contamination of the waters investigated (phthalates and compounds containing a tert-butyl group and chlorine). Oxygen-containing compounds may have therapeutic effects on the human body. The comparative analysis with Far Eastern hot springs showed both great similarities in the distribution of organic compounds and differences due to the contribution of plant detritus to the formation of the organic component of Far Eastern thermal waters.
The article considers the issues of determining the characteristics of target horizons using methods capable of learning on large volumes of heterogeneous data and high prediction accuracy. The methods are used to solve problems of seismic facies analysis at oil and gas fields, the main purpose of which is to reconstruct the sedimentation rocks and predict lithofacies in the study area. The object of the study was one of the fields in the Volga-Ural region. An improved Bayesian classifier was used as a tool. It was used to determine promising distribution zones of the reservoir of the productive formation B2 of the Bobrikovian deposits of the Lower Carboniferous and to assess the hydrocarbon production potential. During the research, the effectiveness of the application of machine learning methods and the proposed improvements was analyzed.
The article considers the problem of distortion of effective velocities estimated from common depth point (CDP) gathers caused by implementation of static corrections for compensation of the influence of near surface velocity anomalies. An analytical solution of the problem of compensation of effective velocities caused by the static correction for shallow and deep velocity anomalies correction is presented. The results of numerical modeling demonstrate the efficiency of the obtained solution. A comparative assessment of the accuracy of time to depth conversion with proposed methodology, without velocity correction and other algorithms for solving the problem is provided
A.A.Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian of Sciences,
Novosibirsk, Russia
Keywords: Dinoflagellate cysts, Campanian, biogeography, paleogeography, correlation
The article presents the results of the analysis of the geographical distribution and taxonomic diversity of dinoflagellate cysts in the Campanian of the Northern Hemisphere. Three types of dinocyst assemblages were established based on the qualitative and quantitative assessment of their generic composition. A wide distribution of some stratigraphically important genera and species, which previously had narrower habitats, was revealed due to transgressive events, expansion of interbasin connections, and the presence of multidirectional meridional currents. The possibility of comparing the North Siberian dinocyst assemblages with those from the stratotypes containing the orthostratigraphic faunal groups of the West European and North American Campanian deposits through the ekaton sections of the Subpolar Cis-Urals and the south of Western Siberia was shown.
A significant problem of the magnetotelluric sounding (MTS) method is the influence of local near-surface inhomogeneities, which distort MTS data across the entire frequency range. These distortions complicate the analysis and interpretation of the data and, ultimately, the retrieval of information about the studied deep structures. A widely used method for suppressing near-surface distortions is the normalization of MTS curves using spatial low-frequency filtering. The aim of the article is to evaluate the effectiveness of this approach, including through the use of weighting characteristics proposed by the authors. A simple geoelectric model of the earth's crust has been compiled, containing a conductive sedimentary cover, a high-resistivity basement, and a three-dimensional conductive depression in the basement. Two model variants were considered: with a homogeneous upper part of the section and with multiple local near-surface inhomogeneities. Using three-dimensional modeling, synthetic magnetotelluric sounding (MTS) data has been calculated for a system of profiles. The data for the second model variant exhibit the effect of near-surface distortions, which leads to a shift in the MTS amplitude curves by level. To suppress the distorting effect from near-surface inhomogeneities, we used normalization of the MTS curves with smoothing filters in a sliding window with different radiuses. Various weight characteristics of the filters were used, namely: for the distance of a point from the center of the sliding window radius, for the difference in amplitude at a given point from the average in the window, and for the difference in the principal directions determined from the polar diagrams of the modulus of the principal component of the impedance tensor and the principal component of the phase tensor. In general, the experimental results showed high efficiency of normalization of the principal components of the impedance tensor and telluric tensor and lower efficiency of normalization of additional components.
Using the laser ablation – inductively coupled plasma – mass spectrometry (LA-ICP-MS) complex, with the involvement of X-ray photoelectron spectroscopy (XPS), new data were obtained on the distribution features and concentration levels of “invisible” gold on the natural surface of arsenopyrite crystals from the Natalka gold deposit (North-East of Russia). It was found that the distribution of Au contents on the surface of the studied sulfide and its concentration levels are closely related to the conditions of the deposit formation. The highest Au concentrations are confined to the surface of arsenopyrite crystals of the hydrothermal stage of ore formation, and the minimum ones are found at the early metamorphic stage. The extreme instability of the gold distribution profile and its content even within the surface of a single crystal is especially pronounced in arsenopyrite of vein and veinlet-vein ores, which is due to the instability of the physicochemical parameters of the hydrothermal ore formation processes at later stages of the deposit formation. Basically, these are oxidation processes that lead to a change in the composition of the primary (as-grown) non-autonomous phases and the redistribution of gold in the surface layer of the crystal, containing highly charged forms of arsenic – As5+
and As3+. The complex and long-term metamorphogenic-magmatic genesis of the giant gold ore deposit Natalka is confirmed. High concentrations of “invisible” gold in the easily destroyed surface layer of sulfides during enrichment are of significant practical interest in the extraction of gold from “refractory” ores, increasing the quality and value of the extracted raw materials.
N.V. Sennikov, O.T. Obut, N.G. Izokh, A.V. Timokhin, I.V. Korovnikov, E.V. Lykova, R.A. Khabibulina
Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
Keywords: Tyva, Ordovician, litho-biostratigraphy, marine sedimentary and volcanic-sedimentary strata
New lithological and biostratigraphic data on stratotype and paleontologically representative marine sedimentary sections of the Malinovka Group (Borlug, Tarlyk and Tamzyrin formations) in the Uyuk area of the region; Shemushdak Group (Ayangaty and Adyrtash formations) and Chergaky Group (Alavelyk Formation) in the Khemchik area of the region; Chergaky Group (Alavelyk Formation) in the Alash area of the region; Kargy Formation in the Kargy area of the region are discussed. The materials on the Sistigkhem Group (Uza, Ust’-Khamsary and Kugar formations) in the Sistigkhem area of Tyva are considered. The chronostratigraphic position of the Tarlag-Aksy Horizon has been clarified and the identification of a new Borlug Horizon has been substantiated. It has been found out that outrcops of the Tyva Ordovician marine sediments are currently located in the number of tectonically isolated blocks and are not fragments of a single paleobasin. Based on the analysis of the taxonomic composition of faunal assemblages and ichnofossils, it is suggested that the Tuvinian Alash-Khemchik, Uyuk and Kargy blocks with outcrops of Ordovician marine sediments were paleozoogeographically close to the marine paleobasins of the Gondwana group of continents. At the same time, a low migration potential of their faunal assemblages relatively to the possibilities of communication with coeval communities of the Altai Basin and of that of
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the Siberian Platform and Taimyr was observed. The Tuvinian Sistigkhem block characterized by effusive-sedimentary sequences of the marine genesis was not only at a significant distance from the listed Siberian paleobasins, but was also separately located from the group of Alash-Khemchik, Uyuk and Kargy blocks with Ordovician marine sediments.
V.V. Marusin 1Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences,Novosibirsk, Russia 2Novosibirsk State University,Novosibirsk, Russia
Keywords: Vendian, Cambrian, General Stratigraphic Scale of Russia, International Chronostratigraphic Chart, small skeletal fossils, trace fossils, chemostratigraphy, Siberian Platform
Nemakit-Daldynian Stage was originally introduced as a regional stage, embracing the lowermost Cambrian strata with the oldest small skeletal fossils, for the Anabar Uplift sections in the 1960s. In subsequent years, it became widespread in the works of Soviet researchers as the terminal Vendian or basal Cambrian stage or regional stage. Almost at the same time, the concept of the Manykaian Stage appeared which is close in its volume and geological meaning to the Nemakit-Daldynian Stage. Although this unit plays a crucial role for our understanding of the chronology of biotic turnovers at the Vendian–Cambrian transition, its status, age, and correlation with the Manykai Stage and units of the International Chronostratigraphic Chart (ICC) remain unclear. This research reveals a historical background revisits the stratigraphic volume and age of the Nemakit-Daldynian Stage. The integrated biostratographic, stable isotope and geochronological data shows this unit belongs to the Upper Vendian and spans the interval from the first appearance of unequivocal anabaritids (~539 Ma) to the first appearance of the Tommotian small skeletal fossils (~530 Ma). In this interpretation, the Nemakit-Daldynian Stage corresponds to the Fortunian Stage of the Cambrian System in the ICC. The base of this unit is coeval to the base of the Rovno Regional Stage of Baltica.
F.I. Zhimulev, A.V. Kotlyarov, M.A. Fidler, N.A. Bekhterev
V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
Keywords: Ophiolites, Altai-Sayan orogen, melanges, olistostromes, subduction, accretionary prism, flysch, oceanic islands, subduction.
The Alambay melange zone (AMZ) is located in the interior of the Early Paleozoic Salair orogeny (Northern part CAOB) and represent the northern extension of the Alambay-Kaim zone, Salair and the Altai Mountains. In paleotectonic terms, Salair is a part of the Kuznetsk-Altai paleo-island arc system. AMZ ophiolites are characterized by the absence of igneous rocks with the geochemical characteristics of MORB, as well as large allochthonous nappes composed of the undisturbed oceanic plate stratigraphy units. Melange complexes play an important role in the geological structure of the AMZ. Two types of melanges, serpentine and clastic, are distinguished in the AMZ. The both types of melanges contain blocks of microquartzites, basalts, limestones; also in clastic mélange a block of garnet amphibolites is found, and in serpentine melange there are blocks of gabbro. Gabbro and garnet amphibolites from AMZ melanges can be classified as island arc rocks based on their geochemical features. Chromite from serpentinized hyperbasites of the zone has an increased content of chromium and magnesium, which is also typical for chromite from suprasubduction hyperbasites. Melange basalts are characterized by high titanium and niobium contents and belong to the OIB type. There are two morphological types of the clastic melanges. The first type is characterized by the predominance of inclusions over the matrix, and the dominance of OIB basalts and limestones in the composition of the inclusions. The second type is characterized by a predominance of matrix over inclusions, and the main type of inclusions are microquartzites (metacherts). To explain the origin of AMZ melanges, the OPS melange model can be used [Wakita, 2015]. This model describes the relations between subduction melanges composition and the position of the decolement, separating subducting plate from the accretionary prism. Within this model, the first type of terrigenous subduction melange is the limestone-basalt type (ls-bs), which is the result of seamount subduction, and the second type corresponds to the sandstone-siliceous type (ss-ch). Formation of sandstone-siliceous melange corresponds to the position of the decolement along the base sedimentary layer of the subducting plate. Subduction melange formed later than 500 million years and earlier than the accumulation of the flysch Late Cambrian-Early Ordovician Green-Violet Group, which allows to estimate the age of the AMZ melange to the Late Cambrian. Wide distribution island-arc rocks as inclusion in the composition of serpentinite and clastic subduction mélanges suggests that the Cambrian subduction zone was characterized by a tectonic erosion regime, in which material from the subduction hanging wall was carried into the subduction zone. The separation faults, along which material was exhumed from subduction channel into the accretionary wedge, were located along the base of the oceanic sediment layer, at the base of the seamounts, and inside the hanging wall of the subduction zone as well.
We present new data on high-barium phlogopites, first discovered in the kimberlite of the Malokuonapskaya pipe. The studied phlogopites can be divided into two groups: 1 – megacrysts up to 2 mm in size with a BaO content of up to 0.58 wt.%, characterized by an increase in the content of this component from the center to the edge (having direct zoning by BaO), and the 2nd group – zonal crystals up to 200 µm in size, containing minerals of the bulk mass of kimberlite, with a BaO concentration of up to 14.6 wt% in the central parts, regularly decreasing to 1 wt% towards the edges of the crystals. The formation of these two generations of micas corresponds to different, unrelated processes. Crystallization of megacrysts took place at the earliest stages of the evolution of the kimberlite melt. A slight increase in Ba concentration from the centers to the edges of phenocrysts may be a consequence of the evolution of kimberlite melt with its enrichment in incompatible elements. Phlogopites of the second group were formed at a later stage, together with the minerals of the groundmass. High barium contents in these phlogopites are possible with a light elements enrichment of the kimberlite melt. The source of these elements could have been the refertilized lithosphere under the influence of the Siberian traps.
40Ar/39Ar dating of phlogopite showed an age of 232.1+2.6 million years.
Configuration of acoustic and magnetic fields, under which in borehole conditions lateral acoustic oscillations emerge in porous saturated medium, is examined. Alternating magnetic field under condition of electroacoustic conversion produces measurable acoustic response at the interface of two media. The character of dependency between amplitude of media interface surface oscillations and medium parameters is described. Possibility of simultaneous measurement of three kinetic coefficients (conductivity, acoustoelectric parameter, permeability) is demonstrated.
1 V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia,
2 Novosibirsk State Technical University, Novosibirsk, Russia
3 Novosibirsk State University, Novosibirsk, Russia
4 Boreskov Institute of Catalysis, Novosibirsk, Russia
5 Synchrotron Radiation Facility SKIF, Boreskov Institute of Catalysis, Koltsovo, Russia
6 Frumkin Institute of Physical Chemistry and Electrochemistry RAS, Moscow, Russia
Keywords: uranium adsorption, uranium oxides, groundwater purification, valent state.
Since apatite is capable to adsorb and retain radionuclides, the removal of uranyl (UO22+) ions from two Ca-containing technogenic and model solutions (1-2 g/L of Ca) was studied when neutralized with sodium hydrogen phosphate solution Na2HPO4. Chemical composition of the sediments was analyzed by XPS and their structure was refined by XRD. The hydroxyapatite formation was confirmed using both XPS and XRD. XRD proves that the two samples contained additional CaH(PO4)•(H2O)2
(brushite), in which calcium changes to uranium of up to 15% in a model solution. When identifying the oxidation state of uranium, the presence of U4+, U5+ и U6+ was noticed with U5+ of up to 30-35 at% from the total amount.
SEM-EDS images of the sediment phases did not allow to determine location of the phases with an uranium content over 18%, for example Ca(UO2)2(PO4)2·11H2O (autunite) or other uranium phosphates. Uranium is detected at the grain rims, indicating a sorption nature of its accumulation. Thermodynamic computations showed the possible formation of independent uranium phases, such as ß-UO2.333, ß-UO2(OH)2 and NaUO2O(OH) (clarkeite), at the measured Eh-pH. The supersaturation of solutions and the spontaneous formation of hydroxyapatite and brushite solid particles lead to a change in the initial Ca/PO4 ratio, where the P/Ca and Ca/O ratios, as well as the
elemental composition in the near-surface layer of three sediments, are not
strictly constant. Newly formed phase contains isolations different in size,
deformation degree, presence of sorption surface groups, which is reflected in
the mechanism of uptake of uranium compounds. No similar study has been
performed with uranium, and our results demonstrate the need for further
studies on the influence of uranium on apatite crystallization. The stability
of phosphate phases shows the high reliability of phosphate safety barriers for
the uranium extraction facilities, and these processes can be used for
remediation areas of aquifers contaminated with radionuclides
1Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia 2Novosibirsk State University, Novosibirsk, Russia
Keywords: Vendian, Cambrian, General Stratigraphic Scale of Russia, International Chronostratigraphic Chart, small skeletal fossils, trace fossils, chemostratigraphy, Siberian Platform
A recent revision of stratigraphic volume and age of the Upper Vendian Nemakit-Daldynian Stage has developed its integrated (bio- and chemostratigraphic) characteristic. This unit comprises the strata between the first appearance of undisputed anabaritids in the fossil record (ca. 539 Ma) and first Tommotian small skeletal fossils of Nochoroicyathus sunnaginicus Assemblage Zone of the Lower Cambrian (ca. 530 Ma). Together with typical assemblages of skeletal fauna, the Nemakit-Daldynian Stage records specific changes in trace fossil assemblages and carbonate carbon isotope composition. Following the formulated criteria, this contribution tests how complete the geological record of the Nemakit-Daldynian Stage is in its reference sections (western Anabar Uplift) and other regions of the Siberian Platform (eastern Anabar Uplift, Olenek Uplift, Kharaulakh Uplift, Uchur-Maya region, Batom Basin, Baikal region, Irkutsk and Biryusa Cis-Sayans uplifts, southern and northern Yenisei Ridge, Turukhansk Uplift, Igarka Uplift, central Siberian Platform).
The article summarizes new data on core and geophysical studies of wells of Famennian deposits in the Yugomashevskoe field located in the Republic of Bashkortostan (Russian Federation). Structurally, the object under consideration belongs to the model of a rimmeded platform with its characteristic elements—organogenic structures and associated facies. The identified sedimentation cyclicity and secondary processes, combined with an analysis of changes in relative sea level, made it possible to identify the most common types of porosity confined to one or another part of the section and facies zonation. Transgressive and regressive parts of the cycles are characterized by their specific set of lithotypes and characteristic types of void space. It was revealed that the formation of void space was influenced by the duration and intensity of secondary processes: leaching, dolomitization, claying associated with the removal of rocks to the surface. In addition, the work substantiates the division of carbonate structures of the study area into three types, differing in position, morphology, as well as in the different manifestations of hupergene transformations, which is reflected in the differentiation of the types of void space of the rocks compose them and their potential in terms of reservoir properties.
N.A. Lykov1,2, Yu. V. Rostovtseva3, I.G. Zakiryanov4, A.V. Timokhin4, A.V. Dronov1, T.V. Gonta4, O.V. Postnikova2 1Geological Institute, Russian Academy of Sciences, Moscow, Russia
2Gubkin Russian State University of Oil and Gas, Moscow, Russia
3Geophysical Center of the Russian Academy of Sciences,Moscow, Russia
4Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
Keywords: сalcified cyanobacteria, Ortonella, Garwoodia, Hedstroemia, bioherms, biostroms, pelecypod banks, Siberian platform, uppermost Middle Ordovician, сyanotoxins
In the Middle Ordovician (Late Darrivillian) deposits (Kirensk-Kudrinian Regional Stage) of the Moyero River section (Tunguska syneclise, Eastern Siberia), the remains of calcareous cyanobacteria of the genera Garwoodia Wood, 1941, Ortonella Garwood, 1914, and Hedstroemia
Rothpletz, 1913 (family Garwoodiaceae) were identified for the first time in thin sections. Previously, Ortonella and Garwoodia were recorded on the Siberian Platform only in Silurian deposits, which makes the discovery of representatives of these genera the earliest for that region. Ortonella
(center part) and Garwoodia (uppermost part) dominate in stromatoporoid-cyanobacterial bioherms, while Hedstroemia occupies a subordinate position. Only Ortonella was found in the biostromes and shelly interlayers of pelecypod banks. The study of the lithology of Kirensk-Kudrinian deposits allowed us to reconstruct a shallow lagoonal type sedimentation environment for the studied part of the section. Under these conditions despite the global increase in biodiversity during the Great Ordovician Biodiversification Event (GOBE), skeletal metazoan organisms failed to become the main framework of biostromes and bioherms. Their role was taken over by cyanobacterial communities resistant to the conditions of extreme shallow-water carbonate-siliciclastic sedimentation regime with terrigenous domination. The growth and subsequent bloom of the latter apparently provoked an increase in phosphorus content in the bottom sediments, which probably caused a local paleoecological crisis of the benthic fauna by the end of the Kirenian time in this part of the paleobasin. This is also confirmed by the depleted ostracod complex in the Moyero River section (in contrast to the same-age deposits of the Lena, Podkamennaya Tunguska, and Kulymbe River sections). The decrease in biodiversity of benthic fauna and, in particular, of skeletal metazoan reef-builders during microbial ‘blooms’ can be explained by the impact of cyanotoxins, which are destructive to marine life. The research demonstrates that even in the epochs of global biota rise, local conditions could limit the participation of skeletal metazoan organisms in the formation of reef ecosystems, preserving the dominance of microbe communities. This emphasizes the role of microbial communities as key agents of carbonate sedimentation during transitional periods of palaeoecological rearrangements and changes in sedimentation type.
V. M. Solovyev, A. S. Salnikov, V. S. Seleznev, T. V. Kashubina, N. A. Galyova, A.E. Shenmaier 1Altai‐Sayan Branch of Geophysical Survey of the Russian Academy of Sciences,Novosibirsk, Russia
2Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
3Seismological Branch of Geophysical Survey of the Russian Academy of Sciences, Novosibirsk, Russia
4A.P. Karpinsky Russian Geological Research Institute, St. Petersburg, Russia
Keywords: deep seismic profile, longitudinal and transverse waves, P- and S-wave velocities and their ratios, deep seismic section, earth's crust, mineragenic zone
The article presents the results of deep seismic studies based on P- and C-wave data on the 500-kilometer Sikhote-Alin fragment of the 8-DV reference geophysical profile. Deep seismic sections of the upper crust (to a depth of 15-20 km) with the distribution of longitudinal and shear wave velocities were constructed. The P-wave velocity over most of the Middle Amur Basin and the East Sikhote-Alin volcano-plutonic belt varies from 4-5 km/s in the uppermost part of the section to 5.8-6.3 km/s at depths of 7-15 km. The Sikhote-Alin orogenic belt in the section along the profile is represented by an anticlinal structure with high-velocity (up to 5.5-5.8 km/s) rocks uplifted in the central part; At great depths of 10-20 km within its limits, the P-wave velocity values were 6.1-6.3 km/s. In the upper part of the section, the S-wave velocity value within the profile as a whole is 2.7–2.9 km/s; reduced values (2.6–2.8 km/s) are observed in the central and eastern parts of the Middle Amur Depression and the eastern section of the East Sikhote-Alin volcano-plutonic belt, increased velocity values up to 3.35 km/s are observed in the central part of the Sikhote-Alin orogenic complex. At depths of 5–15 km within the section, the S-wave velocity increases to 3.4–3.65 km/s. The same behavior of the upper part of the earth's crust to a depth of 15–20 km was established by the values of P- and S-wave velocities, their ratio, and Poisson's ratio. The analysis of the relationship between the identified anomalies and the location of large mineragenic zones of the Amur region was carried out in the profile section. The previously established correspondences on the 2-DV, 3-DV, 1-SB and Vostochno-Stan fragment profile 8-DV on the confinement of ore deposit series to zones of low P- and S-Stan velocity ratios and Poisson's ratio in the upper part of the earth's crust were confirmed. The relationship between the identified surface seismic anomalies and deep (at depths of 5–20 km) roots (intermediate magmatic foci), which can be considered ore-supplying, was substantiated..
The quasi-equilibrium directional crystallization method was used to model a new type of zoning in the Cu-Fe-Ni-S system. A melt with the following composition (in at.%) was crystallized: 14.00 Cu, 30.00 Fe, 4.00 Ni, 51.00 S, and 0.1 each of Pt, Pd, Ag, Au, As, Te, Bi, Pb, Se, and Sn. Optical and electron microscopy, micro-X-ray spectral analysis, differential thermal analysis, and powder diffraction methods were used to analyze the composition and structure of the ingot. Based on the results of measuring the average solid phase composition, the distribution curves of macrocomponents in the ingot in the interval g from 0 to 0.81 (g is the fraction of crystallized melt) were plotted. The change of melt composition and distribution coefficients between solid phases and melt in the process of directed crystallization was also calculated. The obtained sample consists of three primary zones: the monosulfide solid solution with a composition ranging from (Fe₀.₇₅Ni₀.₁₀Cu₀.₀₆)0.91S to (Fe₀.₆₉Ni₀.₁₅Cu₀.₀₉)0.93S (Mss) the Zone I, and two intermediate solid solutions: ~ (Fe₀.₅₇Ni₀.₀₃Cu₀.₄₅)1.05S (Iss1) the Zone II and (Fe₀.₄₆Ni₀.₀₆Cu₀.₅₂)1.05S (Iss2) the Zone III. The peritectic character of the crystallization of Iss1 and Iss2
from the melt was established. The trajectories of melt and solid phases composition and series of conodes are plotted for Mss and Iss1 on the phase diagram of Cu-Fe-Ni-S system. Secondary zonality is described by the following sequence of phases: Pyh 1C + Pyh 3C + Icb + Ccp / Ccp + Iss + Fe-Pn, Sug / Ccp + Ni-Pn +NiS+Bn (Pyh - hexagonal pyrrhotite, Icb - isocubanite, Ccp - chalcopyrite, Pn - pentlandite, Sgk - sugakiite, Bn - bornite) and belongs to the high-sulfur pyrrhotite+cubanite-chalcopyrite type of ore body zonation.
I.E. Lebedev1, V.E. Pavlov1, P.L. Tikhomirov1, A.M. Pasenko1, U.S. Efremova2
1Schmidt Institute of Physics of the Earth, Russian Academy of Sciences, Moscow, Russia 2Institute of the Earth’s Crust, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russia
Keywords: North-East of Eurasia, Bering Sea region, Okhotsk-Chukotka volcanic belt, Valunistoe deposit, paleomagnetism, geochronology.
This paper presents new geochronological and paleomagnetic data that support the idea of later termination of magmatism in the Okhotsk-Chukotka Volcanic Belt (OCVB) within the East Chukotka flank zone than previously thought. It also allows the calculation of a new paleomagnetic pole (78.6°N, 212.2°E, A95= 4.7°, N=104) with an age of ~72 Ma for the vicinity of the Valunistoe deposit. Combined with paleomagnetic data previously obtained by us for the Kupol deposit area, the new results lead to the following conclusions: 1. The studied areas (the "Kupol" and "Valunistoe" location) have experienced relatively small, but statistically significant, displacements relative to the North American plate during the time interval from the Late Cretaceous to the present. 2. The "Kupol" location is rotated counterclockwise by several to a few tens of degrees relative to the North American plate, while the "Valunistoe" location is displaced relative to this plate in latitude by a distance of at least several hundred kilometers. 3. Based on the obtained data, we propose a model, building on the existing Bering Sea region model of Redfield and Fitzgerald (1993), according to which the "Kupol" and "Valunistoe" locations belong to the boundary area between the North American plate and the Bering plate, represented by a series of tectonic blocks. The tectonic block to which the "Valunistoe" location belongs is one of the westernmost blocks grouped into the Bering plate, while the "Kupol" location belongs to the easternmost regions of the Chukotka deformed margin of the North American plate. Deformations arising in the interaction of these tectonic blocks in the region under consideration are mainly diffuse. The Trans-Bering Seismic Belt appears to be a potential area where the discussed deformations may be most concentrated.
The impact facies are subdivided to coptogenic (primarily deposited) and coptomictic (redeposited) units. The redeposited impact facies remain poorly studied at present. In this work, the deposits of the coptomictic facies on the basis of the Kara astrobleme are characterized in detail for the first time. Structural and textural features of impactites at the macrolevel and microscopic structural and material features of the constituent components (lithoclasts, vitroclasts and matrix) of lapilli and agglomerate suevites of the Sayakha River area are considered. According to the reconstruction, the breccia impactites of the crater rim at the northwestern sector of the Kara astrobleme were formed under conditions of the landslides facies from the crater wall at the stage of early modification of the astrobleme. The results obtained can be used to reconstruct a model of the Kara impact structure formation and to improve the unified model of the breccia impactites formation of coptomictic facies in a large meteorite crater.
Within the framework of the elastic-plastic model of the behavior of the medium, the influence of the non-uniform distribution of properties and the geometry of the problem on the stress-strain state of a 500 km thick block model under the action of gravity is considered. Calculations were carried out in a 2D formulation of a plane stress state for a rectangular and cylindrical profile, taking into account the curvature of the Earth's surface. It is shown that anomalies in the stress-strain state and zones of development of irreversible deformation are determined primarily by the heterogeneity of the structure, the presence of density and rheological anomalies. The geometry of the models, taking into account the curvature of the lithosphere significantly affects primarily the stress state in the crust, where the greatest shear strength is, which determines the development of irreversible deformation depending on the heterogeneity of the medium.
In this work, to assess the influence of the geometric factor on the stress-strain state of the lithosphere, numerical modeling of its seismic model along the Craton profile, 3600 km long and 500 km deep, presented in rectangular and cylindrical coordinates, was carried out. A comparison of the obtained solutions was carried out.
The change in the stress-strain state during the rise and immersion of a block of the medium with a cylindrical formulation of the problem is considered. It is shown that vertical displacements with such a formulation have a noticeable effect on horizontal stresses and can lead to the development of irreversible deformation.
It is shown that with successive layer-by-layer build-up of the crust, the deviation of tangential stresses in a cylindrical setting from horizontal stresses of a flat model at the surface is negligibly small. The maximum deviation occurs at the middle of the depth of the deformed layer.
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