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Chemistry for Sustainable Development

2018 year, number 5

Preparation of Fused Hafnium (IV) Carbide from Mechanochemically Synthesized Hf/C Composite

A. I. ANCHAROV1,2, G. N. GRACHEV3, S. V. VOSMERIKOV1, and T. F. GRIGOR’EVA1
1Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
E-mail: ancharov@mail.ru
2Budker Institute of Nuclear Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
3Institute of Laser Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Keywords: mechanochemical synthesis, hafnium, carbon, Hf/C mechanocomposite, nanoscale and fused hafnium carbide, photon flux irradiation
Pages: 545-549

Abstract

Mechanochemical preparation of nanoscale hafnium (IV) carbide was explored. It was demonstrated that the Hf/C mechanocomposite with a wide particle-size distribution was formed in the first step. Fused hafnium (IV) carbide was produced from nanoscale hafnium (IV) carbide and the hafnium/carbon mechanocomposite by treatment with high-intensity photon flux. According to research results, the mechanocomposite is more preferable and may be used as a precursor to make products of fused hafnium (IV) carbide using additive technologies.


DOI: 10.15372/CSD20180514