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Chemistry for Sustainable Development

2018 year, number 4

Formation of Gas Hydrate – Oil Associates in the Aqueous Phase During the Grow of Gas Hydrate Crystals in Water – Oil – Methane System

T. P. ADAMOVA1, A. YU. MANAKOV1,2, A. A. SIZIKOV1, L. K. ALTUNINA3
1Nikolaev Institute of Inorganic Chemistry, SB RAS, Novosibirsk, Russia
2Novosibirsk State University, Novosibirsk, Russia
3Institute of Petroleum Chemistry, SB RAS, Tomsk, Russia
Keywords: газовый гидрат, метан, нефть, рост кристаллов, gas hydrate, methane, crude oil, crystal growth
Pages: 353-360

Abstract

Video fixation of the growth of methane hydrate in three-phase water–oil–methane systems was carried out. Three kinds of crude oil were taken for experiments. The formation of unusual associates of gas hydrate with oil, growing into the volume of the aqueous phase, was found to be possible in two of these oil kinds at the late stages of hydrate growth. Possible mechanisms for the formation of these associates are discussed.

DOI: 10.15372/CSD20180401