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Chemistry for Sustainable Development

2018 year, number 3

Nanopesticides Based on Supramolecular Complexes of Tebuconazole for Cereal Seed Treatment

E. S. METELEVA1, V. I. EVSEENKO1, O. I. TEPLYAKOVA2, S. S. KHALIKOV3, N. E. POLYAKOV4, I. E. APANASENKO4, A. V. DUSHKIN1, N. G. VLASENKO2
1Institute of Solid State Chemistry and Mechanochemistry, SB RAS, Novosibirsk, Russia
2Research Institute of Agriculture and Chemicalization of Agriculture, SB RAS, Krasnoobsk, Russia
3Institute of Organoelement Compounds. A. N. Nesmeyanov Academy of Sciences, Moscow, Russia
4Institute of Chemical Kinetics and Combustion SB RAS, Novosibirsk, Russia
Keywords: тебуконазол, механохимия, полисахариды, сапонины, комплексы включения, супрамолекулярные системы, фунгицидные композиции, биологическая эффективность, продуктивность, Tebuconazole, mechanochemistry, polysaccharides, saponins, inclusion complexes, supramolecular systems, fungicidal compositions, biological efficiency, productivity
Pages: 256-270

Abstract

To create innovative complex seed protectants, a mechanochemical method for obtaining intermolecular supramolecular complexes of tebuconazole (TBC) was used. The use of polysaccharide arabinogalactan, glycyrrhizic acid and its disodium salt, as well as a dry extract of licorice root as substances forming supramolecular systems, including TBC molecules in their structure, made it possible to obtain preparations of seed disinfectants with improved ecological and biological properties. The obtained TBC-based compositions showed high efficacy against pathogenic microflora in laboratory and field conditions in the treatment of spring wheat and barley seeds, in suppression of the development of ordinary root rot, the absence of a retardant effect and a positive effect on the productivity of these crops. In addition, the compositions can reduce the rate of discharge of TBC up to 2 times.

DOI: 10.15372/CSD20180304