Publishing House SB RAS:

Publishing House SB RAS:

Address of the Publishing House SB RAS:
Morskoy pr. 2, 630090 Novosibirsk, Russia



Advanced Search

Journal of Structural Chemistry

2017 year, number 4

IR SPECTROSCOPIC STUDY OF Н COMPLEXES OF DIOXOLANE DERIVATIVES WITH METHANOL IN СCl4 SOLUTIONS

N. U. Mulloev, J. Yusupova, B. I. Makhsudov
Tajik National University, Dushanbe, Republic of Tajikistan
Keywords: гетероциклические соединения, протоноакцепторная способность, производные диоксоланов, индукционное влияние, стерический фактор, heterocyclic compounds, proton acceptor ability, derivatives of dioxolanes, inductive effect, steric factor

Abstract

The effect of the formation of Н complexes of some dioxolane derivatives with methyl alcohol on the parameters of stretching bands of the ОН group is studied. The observed changes in the spectral and energy characteristics of the complexes are due to the inductive effect of the introduced structural fragments on the equilibrium electron configuration of the COC group in position 1 of the proton acceptor. Based on the results obtained, the authors make the conclusion that the compounds studied are weak proton acceptors.