CRYSTAL STRUCTURE OF THE COPPER(II) COMPLEX WITH ACETYLACETONE AND ETHYLENEDIAMINE OBTAINED BY TEMPLATE SYNTHESIS
A. M. Maharramov1, M. G. Tsintsadze2, R. A. Alieva1, F. N. Bahmanova1, F. O. Mamedova3, R. K. Askerov1, F. S. Alieva1, F. M. Chyragov1
1Baku State University, Baku, Azerbaijan
2Georgian Technical University, Tbilisi, Georgia
3Gandzha State University, Gandzha, Azerbaijan
Keywords: РСА, монокристалл, медь, сингония, синтез, single crystal XRD analysis, single crystal, copper, crystal symmetry, synthesis
Abstract
A new copper(II) complex with acetylacetone and ethylenediamine is obtained using the template synthesis. It is studied by single crystal X-ray diffraction. The crystals are monoclinic: а = 7.7563(4) Å, b = 24.0157(12) Å, c = 24.6353(13) Å, β = 91.9490(10)°, V = 4586.2(4) Å3, space group P2(1)/c, Z = 2, dcalc = 1.713 g/cm3, R = 0.0695. The copper atom environment consists of two oxygen and two nitrogen atoms of the ligand, forming a slightly distorted square.
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