HEXANUCLEAR Na(I) COMPLEX WITH 3,5-DIMETHYL-1H-PYRAZOLE AND ITS ANION
K. A. Vinogradova, P. A. Stabnikov, N. I. Alferova, D. Yu. Naumov, Yu. M. Rumyantsev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Keywords: комплекс натрия(I), 3,5-диметил-1-пиразол, 3,5-диметил-1-пиразолят-анион, кристаллическая структура, летучесть, sodium(I) complex, 3,5-dimethyl-1-pyrazole, 3,5-dimethyl-1-pyrazolate anion, crystal structure, volatility
Abstract
The crystal structure of a hexanuclear Na(I) complex based on 3,5-dimethyl-1H-pyrazole (C5H8N2) and its anion is determined (space group P21/c, a = 12.2194(5) Å, b = 24.1554(9) Å, c = 11.3311(4) Å, β = 109.942(1)°, V = 3143.99(8) Å3, Z = 2). The crystal structure is formed by Na6(C5H8N2)4(C5H7N2)6 molecules. Thermogravimetric studies show that the compound exhibits volatility at elevated temperatures. The compound can be used in chemical gas-phase deposition processes.
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