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Journal of Structural Chemistry

2017 year, number 4

CRYSTAL STRUCTURE OF NA3[TAO8]x14H2O

P. A. Abramov1,2, A. A. Shmakova1,2, M. N. Sokolov1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Russia, Novosibirsk, Russia
Keywords: тантал, натрий, пероксокомплекс, кристаллическая структура, tantalum, sodium, peroxocomplex, crystal structure

Abstract

The slow diffusion of ethanol vapor into a Na8[Ta6O19]x24.5H2O solution in 30% hydrogen peroxide leads to the formation of colorless Na3[TaO8]x14H2O crystals (1) whose structure and composition are determined by single crystal XRD.