CRYSTAL STRUCTURES OF BINUCLEAR Bi(III) CHLORIDE AND BROMIDE COMPLEXES WITH SOME CATIONS - ALKYLATED PYRIDINE DERIVATIVES
S. A. Adonin1,2, I. D. Gorokh2, D. G. Samsonenko1,2, I. V. Korol`kov1,2, M. N. Sokolov1,2,3, V. P. Fedin1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk, Russia
3Kazan Federal University, Kazan, Russia
Keywords: висмут, галогенидные комплексы, полиядерные комплексы, ароматические катионы, bismuth, halide complexes, polynuclear complexes, aromatic cations
Abstract
By a reaction of [BiX6]3- with salts of various N-alkylated pyridine derivatives in 2M HX (X = Cl, Br), (N-BzPy)4[Bi2X10] complexes (X = Cl (1), Br (2), (4-MePyH)4[Bi2Cl10] (3)) are obtained and structurally characterized.
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