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Journal of Structural Chemistry

2017 year, number 3

CRYSTAL STRUCTURE OF 2,8,9-TRIOXA-5-AZA-1-SILABICYCLO[3.3.3]UNDEC-1-YLMETHYL-2-METHYLACRYLATE

Yu. I. Bolgova, T. N. Borodina, O. M. Trofimova, V. I. Smirnov
Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia
Keywords: (1-силатранилметил)метакрилат, кристаллическая структура, рентгеноструктурный анализ, (1-silatranylmethyl)methacrylate, crystal structure, X-ray diffraction analysis

Abstract

The XRD method is used to determine the molecular and crystal structure of 2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undec-1-ylmethyl-2-methylacrylate (H2C=C(Me)C(O)OCH2Si(OCH2CH2)3N). The crystallographic data are as follows: space group Р212121, а = 9.7659(1) Å, b = 10.017(1) Å, с = 17.915(2) Å, V = 1753.3(3) Å3, Z = 4. The coordination polyhedron of the silicon atom is a distorted trigonal bipyramid. The length of the N→Si coordination bond is 2.099 Å.