CRYSTAL STRUCTURE OF BINUCLEAR BISMUTH COMPLEXES [H2dabco]2[Bi2Cl10]x2H2O AND (H3O)2[H2dabco]4[Bi2Br10][BiBr6]2x4.5H2O
E. A. Kovalenko1, D. V. Kochelakov1,2, D. G. Samsonenko1,2, V. P. Fedin1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk, Russia
Keywords: синтез, висмут, dabco, рентгеноструктурный анализ, кристаллическая структура, synthesis, bismuth, dabco, X-ray crystallographic analysis, crystal structure
Abstract
Binuclear bismuth complexes [H2dabco]2[Bi2Cl10]x2H2O and (H3O)2[H2dabco]4[Bi2Br10] x [BiBr6]2x4.5H2O are obtained by heating (100 °C) acidic solutions of a mixture of bismuth chloride and bromide with dabco. The structure of the complexes is determined by single crystal X-ray diffraction.
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