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Journal of Structural Chemistry

2017 year, number 3

CRYSTAL AND MOLECULAR STRUCTURE OF A NEW PALLADIUM(II) COMPLEX WITH A COUMARIN-VALINE DERIVATE

D.Lj. Stojkovic1, V.V. Jevtic1, N. Vukovic1, M. Vukic1, I. Potocnak2, I.R. Zelen1, M.M. Zaric1, M.M. Misic3, D. Baskic4,5, G.N. Kaluderovic6, S.R. Trifunovic1
1University of Kragujevac, Kragujevac, Serbia
2Institute of Chemistry, Kosice, Slovakia
3Public Health Institute, Vranje, Serbia
4Centre for Molecular Medicine and Stem Cell Research, Kragujevac, Serbia
5Public Health Institute, Kragujevac, Serbia
6Leibniz Institute of Plant Biochemistry, Halle, Germany
Keywords: coumarine-derived ligand, palladium(II) complex, crystal structure

Abstract

The new coumarine derivate with methyl ester of 2-(( Z )-1(2,4-dioxochroman-3-ylidene)ethylamino)-3-methylbutanoic acid and the corresponding palladium(II) complex are synthesized and characterized by microanalysis, infrared, 1H and 13C NMR spectroscopy. The proposed structure of the ligand was confirmed based on the X-ray structural study.