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Chemistry for Sustainable Development

2017 year, number 1

Application Peculiarities of in situ XPS and Mass Spectrometry Methods to Study Concentration Hysteresis in Methane Oxidation over Alumoplatinum Catalysts

I. A. CHETYRIN1,2, I. P. PROSVIRIN1,2, I. YU. PAKHARUKOV1,2, and V. I. BUKHTIYAROV1,2
1Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk State University, Novosibirsk, Russia
Keywords: X-ray photoelectron spectroscopy, mass spectrometry, concentration hysteresis, alumoplatinum catalysts
Pages: 91-99

Abstract

The study of concentration hysteresis in methane oxidation over alumoplatinum catalysts was conducted. It was determined that catalysts activation was accompanied by partial platinum reduction, the boundaries of existence of concentration hysteresis and effect on them of the particle size of the active component were defined.