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Journal of Structural Chemistry

2016 year, number 8

NEW DATA ON THE STRUCTURE OF a-trans-[Pd(NH3)2Cl2]

D. Yu. Naumov1, S. P. Khranenko1, N. V. Kuratieva1,2, A. V. Panchenko1,2, S. A. Gromilov2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk,Russia
Keywords: палладий, рентгеноструктурный анализ, кристаллохимия, неупорядоченная структура, palladium, X-ray diffraction analysis, crystal chemistry, disordered structure

Abstract

Single crystal X-ray diffraction was applied for re-determination of the crystal structure of a- trans -[Pd(NH3)2Cl2]. It has been demonstrated that, in contrast to the literature data, the structure is disordered. This model does not require excess over-stoichiometric palladium. Two crystals obtained in the same experiment illustrate possible variations in the packing of the molecules of the complex.