STRUCTURE AND LOCATION OF PROTON HYDRATES IN TRITON N-42 REVERSE MICELLES DURING INJECTION SOLUBILIZATION OF HCL SOLUTIONS
T. Yu. Podlipskaya, A. I. Bulavchenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Keywords: обратные мицеллы, оксиэтилированные ПАВ, солюбилизация, ИК-Фурье спектроскопия, ассоциаты гидратированного протона, reverse micelles, ethoxylated surfactants, solubilization, FTIR spectroscopy, hydrated proton associates
Abstract
A Fourier IR spectroscopic study has shown that during injection solubilization of HCl solutions ( V s/ V o = 1.0-3.5 vol.%) at a concentration of 1-4 M by Triton N-42 reverse micelles in n -decane, the number of water molecules bound to protons is equal to 2.7±0.1. Protons form (70%) and (30%) cations in equilibrium, which are localized in the aqueous cores of the micelles.
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