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Combustion, Explosion and Shock Waves

2016 year, number 6

Chemical Conversion of SO2 in Low-Temperature Low-Pressure Oxyhydrogen Flames. 2. Mechanism of Formation of Elemental Sulfur

A. A. Mantashyan, E. M. Makaryan, A. A. Arutyunyan, G. M. Gevorgyan
Nalbandyan Institute of Chemical Physics, Yerevan, 0014 Armenia
Keywords: сера, диоксид серы, цепная реакция, свободные радикалы, низкотемпературное пламя, sulfur, sulfur dioxide, chain reaction, free radicals, low-temperature flame

Abstract

Kinetic analysis of the mechanism of chemical conversion of SO2 in a coupled radical-chain process in low-temperature low-pressure oxyhydrogen flames has been performed. The set of possible elementary reactions is considered, and the main routes of SO2 conversion to elemental sulfur are identified.

DOI: 10.1134/S0010508216060046