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Journal of Structural Chemistry

2016 year, number 5

Characterization, luminescent properties, crystal structure determination, and thermal properties of [Tl(Ph2phen)Cl3(DMSO)]

M. Ghadermazi
University of Kurdistan, Sanandaj, Iran
Keywords: synthesis, Tl(III), 4,7-diphenyl-1,10-phenanthroline, crystal structure, thermal gravimetric, differential thermal analysis, luminescent properties


The new mixed-ligand complex of [Tl(Ph2phen)Cl3(DMSO)] (1) is obtained from the reaction of TlCl3×4H2O with 4,7-diphenyl-1,10-phenanthroline (Ph2phen) in a methanol solution. Suitable crystals of 1 are obtained for the X-ray diffraction measurement by methanol diffusion into a DMSO solution. This complex is characterized by spectral methods (IR, UV-Vis, 1H NMR, and luminescence), elemental analysis, thermal analysis (TG, DTA), and single crystal X-ray diffraction.