NICKEL(II) COMPLEX CONTAINING 5,5'-DIMETHYL-2,2'-BIPYRIDINE: CRYSTAL STRUCTURE AND LUMINESCENT PROPERTIES
A. Abedi, E. Saemian, V. Amani
Islamic Azad University, P.O. Box: 19585-936, Tehran, Iran
Keywords: nickel(II), 5,5'-dimethyl-2,2'-bipyridine, crystal structure, luminescent properties
Abstract
[Ni(5,5'-dmbipy)2Cl2]×3H2O (1) complex was obtained from the reaction of NiCl2×6H2O with 5,5'-dimethyl-2,2'-bipyridine (5,5'-dmbipy) in a mixture of CH3OH/CH3CN. This complex was characterized by elemental analysis, IR, UV-Vis and luminescence spectroscopy, and its structure was determined by the single-crystal diffraction method. The Ni atom has a distorted octahedral coordination by four N atoms from two 5,5'-dmbipy ligands and two Cl- anions.
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