CRYSTAL STRUCTURE OF THE INCLUSION COMPOUND OF A POROUS METAL-ORGANIC POLYMER WITH CYMANTRENE
I. S. Khan1,2, D. G. Samsonenko1, V. M. Pakomova3, V. P. Fedin1
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk, Russia
3Kazan State Agricultural University, Kazan, Russia
Keywords: кристаллическая структура, пористые координационные полимеры, соединение включения, цимантрен, цинк, crystal structure, porous coordination polymers, inclusion compounds, cymantrene, zinc
Abstract
The inclusion compound of the composition [Zn2(dmf)(bdc)(lac)]×[Mn(C5H5)(CO)3] (C5H5 = cyclopentadienyl) is obtained by keeping a mixture of crystals of a porous homochiral metal-organic polymer of the composition [Zn2(dmf)(bdc)(lac)]×DMF (DMF = N,N¢-dimethylformamide, H2bdc = terephthalic acid, H2lac = S -lactic acid) with the excess of cymantrene at 100°C, and the crystal structure of this compound is determined.
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