RELATIVISTIC EFFECTS IN OXIDES AND HALIDES OF TRANSITION AND POST-TRANSITION METALS
S. G. Kozlova, M. R. Ryzhikov, V. A. Slepkov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Keywords: релятивистские эффекты, электронное строение, полиморфизм, магнетизм, стереохимически активные неподеленные электронные пары, relativistic effects, electronic structure, polymorphism, magnetism, stereochemically active lone pairs
Abstract
The review presents the experimental and theoretic data on relativistic effects in solids, which were the objects of S. P. Gabuda’s studies. Coordination and cluster compounds are considered. Unique data obtained by nuclear magnetic resonance, vibrational spectroscopy, magnetochemistry and other methods are presented. The possibilities of the occurrence of polymorphic phase transitions, the Jahn-Teller effect, intermolecular interactions, and other effects due to the features of structure of relativistic wave functions are discussed.
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