CRYSTAL AND MOLECULAR STRUCTURE OF 1-(IODMETHYL)- AND 1-(IODPROPYL)SILATRANES
I. V. Sterkhova1, V. I. Smirnov1, G. A. Kuznetsova1, E. A. Zel’bst2
1Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia
2Pedagogical Institute, Irkutsk, Russia
Keywords: 1-(иодметил)силатран, 1-(иодпропил)силатран, молекулярная структура, рентгеноструктурный анализ, 1-(iodmethyl)silatrane, 1-(iodpropyl)silatrane, molecular structure, single crystal X-ray diffraction analysis
Abstract
The crystal and molecular structures of 1-(iodmethyl)silatrane and 1-(iodpropyl)silatrane are determined by X-ray diffraction. The effect of the iodine heteroatom upon silatrane moieties of the molecules through one- and three-carbon chains is studied based on the geometric characteristics of the molecules and the analysis of their packings.
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