COMPLEX (PHENH)4[RE4TE4(CN)12]x4H2O
Yu. M. Litvinova1, N. V. Kuratieva1, Ya. M. Gayfulin1, Yu. V. Mironov1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk, Russia
Keywords: рений, кубановый кластерный комплекс, кристаллическая структура, rhenium, cubane cluster complex, crystal structure
Abstract
A tetrahedral cluster complex of rhenium with the composition (PhenH)4[Re4Te4(CN)12]×4H2O (1) is obtained and structurally characterized. The structure of the salt is determined by single crystal X-ray diffraction. The compound crystallizes in the orthorhombic space group Fdd 2, a = 23.1780(7) Å, b = 50.009(2) Å, c = 11.4274(3) Å, V = 13245.6(7) Å3.
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